The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure-Property Relationships and Applications

Ashanul Haque; Idris Juma Al-Busaidi; Rayya A. Al-balushi; Muhammad S Khan; Paul Raithby

doi:10.1021/acs.chemrev.8b00022

The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure-Property Relationships and Applications

Ashanul Haque, Idris Juma Al-Busaidi, Rayya A. Al-balushi, Muhammad S Khan, Paul Raithby

Sultan Qaboos University

Research output: Contribution to journal › Review article › peer-review

153 Citations (SciVal)

689 Downloads (Pure)

Abstract

Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their intriguing and tunable chemical and photo-physical properties. This review highlights fascinating advances made in the field of conjugated organic poly-ynes and poly(metalla-ynes) incorporating group 4-11 metals. This includes several important aspects of conjugated poly-ynes viz. synthetic protocols, bonding, electronic structure, and nature of luminescence, structure-property relationships, diverse applications, and concluding remarks. Furthermore, we delineated the future directions and challenges in this particular area of research.

Original language	English
Pages (from-to)	8474-8597
Number of pages	24
Journal	Chemical Reviews
Volume	118
Issue number	18
Early online date	16 Aug 2018
DOIs	https://doi.org/10.1021/acs.chemrev.8b00022
Publication status	Published - 26 Sept 2018

Keywords

Poly-yne
Poly(Metalla-ynes)
Structure
Properties

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10.1021/acs.chemrev.8b00022

Chem Rev Accepted Version 150618
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemical Reviews, copyright (C) American Chemical Society after peer review and technical editing by the publisher. to access the final edited and published work see: https://doi.org/10.1021/acs.chemrev.8b00022
Accepted author manuscript, 11.5 MB

Cite this

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title = "The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure-Property Relationships and Applications",

abstract = "Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their intriguing and tunable chemical and photo-physical properties. This review highlights fascinating advances made in the field of conjugated organic poly-ynes and poly(metalla-ynes) incorporating group 4-11 metals. This includes several important aspects of conjugated poly-ynes viz. synthetic protocols, bonding, electronic structure, and nature of luminescence, structure-property relationships, diverse applications, and concluding remarks. Furthermore, we delineated the future directions and challenges in this particular area of research.",

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AU - Al-balushi, Rayya A.

AU - Khan, Muhammad S

AU - Raithby, Paul

PY - 2018/9/26

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KW - Poly(Metalla-ynes)

KW - Structure

KW - Properties

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The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure-Property Relationships and Applications

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Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

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The Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure-Property Relationships and Applications

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Applying Long-Lived Metastable States in Switchable Functionality via Kinetic Control of Molecular Assembly

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