The rhodium-catalysed 1,2-addition of arylboronic acids to aldehydes and ketones with sulfonated S-Phos

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Abstract

The rhodium-catalysed 1,2-addition of arylboronic acids to aryl aldehydes has been accomplished in high yield using sulfonated S-Phos, a water-soluble biaryl phosphine ligand which allows for catalyst recycling. The catalytic protocol has also been successful in the challenging arylation of ketones.
Original languageEnglish
Pages (from-to)7365-7368
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number52
DOIs
Publication statusPublished - 30 Dec 2009

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phosphine
Rhodium
Recycling
Ketones
Aldehydes
Ligands
Catalysts
Acids
Water

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The rhodium-catalysed 1,2-addition of arylboronic acids to aldehydes and ketones with sulfonated S-Phos. / White, J.R.; Price, G.J.; Plucinski, P.K.; Frost, C.G.

In: Tetrahedron Letters, Vol. 50, No. 52, 30.12.2009, p. 7365-7368.

Research output: Contribution to journalArticle

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