The reduction of (μ2-NO) in [Ru3(Co)10(μ2-NO)2] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru4n(CO)12(μ2-NO)] and [Ru4n(CO)12(μ2-NCO)]

Julian P. Attard; Brian F.G. Johnson; Jack Lewis; Julian M. Mace; Paul R. Raithby

doi:10.1039/C39850001526

The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]

Julian P. Attard, Brian F.G. Johnson, Jack Lewis, Julian M. Mace, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Ru₃(CO)₁₀(μ₂-NO)₂] reacts with CO to form the species [Ru₃(CO)₁₂], [Ru₃(CO)₁₀(μ2-NO)(μ₂-NCO)], [Ru₄N(CO)₁₂(μ2-NO)], and [Ru₄N(CO)₁₂(μ2-NCO)], evidence suggesting the formation of a reactive nitrido- or nitrene-nitrosyl intermediate; X-ray analysis shows that both of the tetranuclear nitrido species adopt a 64-electron ‘butterfly’ structure in which the ‘hinge’ metal-metal vector is long and supports a (μ2-NO) or a (μ2-NCO) bridging group.’.

Original language	English
Pages (from-to)	1526-1528
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39850001526
Publication status	Published - 1985

ASJC Scopus subject areas

Molecular Medicine

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Attard, J. P., Johnson, B. F. G., Lewis, J., Mace, J. M., & Raithby, P. R. (1985). The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]. Journal of the Chemical Society - Series Chemical Communications, (21), 1526-1528. https://doi.org/10.1039/C39850001526

The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]. / Attard, Julian P.; Johnson, Brian F.G.; Lewis, Jack et al.
In: Journal of the Chemical Society - Series Chemical Communications, No. 21, 1985, p. 1526-1528.

Research output: Contribution to journal › Article › peer-review

Attard, JP, Johnson, BFG, Lewis, J, Mace, JM & Raithby, PR 1985, 'The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]', Journal of the Chemical Society - Series Chemical Communications, no. 21, pp. 1526-1528. https://doi.org/10.1039/C39850001526

Attard JP, Johnson BFG, Lewis J, Mace JM, Raithby PR. The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]. Journal of the Chemical Society - Series Chemical Communications. 1985;(21):1526-1528. doi: 10.1039/C39850001526

Attard, Julian P. ; Johnson, Brian F.G. ; Lewis, Jack et al. / The reduction of (μ₂-NO) in [Ru₃(Co)₁₀(μ₂-NO)₂] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru₄n(CO)12(μ₂-NO)] and [Ru₄n(CO)₁₂(μ₂-NCO)]. In: Journal of the Chemical Society - Series Chemical Communications. 1985 ; No. 21. pp. 1526-1528.

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title = "The reduction of (μ2-NO) in [Ru3(Co)10(μ2-NO)2] by carbon monoxide; evidence for the formation of a triruthenium nitrido intermediate, and the structural characterisation of [Ru4n(CO)12(μ2-NO)] and [Ru4n(CO)12(μ2-NCO)]",

abstract = "The cluster [Ru3(CO)10(μ2-NO)2] reacts with CO to form the species [Ru3(CO)12], [Ru3(CO)10(μ2-NO)(μ2-NCO)], [Ru4N(CO)12(μ2-NO)], and [Ru4N(CO)12(μ2-NCO)], evidence suggesting the formation of a reactive nitrido- or nitrene-nitrosyl intermediate; X-ray analysis shows that both of the tetranuclear nitrido species adopt a 64-electron {\textquoteleft}butterfly{\textquoteright} structure in which the {\textquoteleft}hinge{\textquoteright} metal-metal vector is long and supports a (μ2-NO) or a (μ2-NCO) bridging group.{\textquoteright}.",

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AB - The cluster [Ru3(CO)10(μ2-NO)2] reacts with CO to form the species [Ru3(CO)12], [Ru3(CO)10(μ2-NO)(μ2-NCO)], [Ru4N(CO)12(μ2-NO)], and [Ru4N(CO)12(μ2-NCO)], evidence suggesting the formation of a reactive nitrido- or nitrene-nitrosyl intermediate; X-ray analysis shows that both of the tetranuclear nitrido species adopt a 64-electron ‘butterfly’ structure in which the ‘hinge’ metal-metal vector is long and supports a (μ2-NO) or a (μ2-NCO) bridging group.’.

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