The Reaction of PtCl2 with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Matthew G. Davidson; Paul R. Raithby; Ronald Snaith; Dietmar Stalke; Dominic S. Wright

doi:10.1002/anie.199116481

The Reaction of PtCl₂ with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Matthew G. Davidson
, Paul R. Raithby
, Ronald Snaith
, Dietmar Stalke
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

A Ca₂ complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl₂ with [Ox₂Ca(HMPA)₂] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt²⁺ with DNA bases. (Figure Presented.)

Original language	English
Pages (from-to)	1648-1650
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	12
DOIs	https://doi.org/10.1002/anie.199116481
Publication status	Published - Dec 1991

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199116481

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title = "The Reaction of PtCl2 with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion",

abstract = "A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)",

author = "Davidson, \{Matthew G.\} and Raithby, \{Paul R.\} and Ronald Snaith and Dietmar Stalke and Wright, \{Dominic S.\}",

year = "1991",

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doi = "10.1002/anie.199116481",

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T2 - Synthesis and Structure of a Complexed CaPt Anion

AU - Davidson, Matthew G.

AU - Raithby, Paul R.

AU - Snaith, Ronald

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1991/12

Y1 - 1991/12

N2 - A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)

AB - A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)

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U2 - 10.1002/anie.199116481

DO - 10.1002/anie.199116481

M3 - Article

AN - SCOPUS:33748215943

SN - 0570-0833

VL - 30

SP - 1648

EP - 1650

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

The Reaction of PtCl₂ with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Abstract

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