The Reaction of PtCl2 with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Matthew G. Davidson; Paul R. Raithby; Ronald Snaith; Dietmar Stalke; Dominic S. Wright

doi:10.1002/anie.199116481

The Reaction of PtCl₂ with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Matthew G. Davidson, Paul R. Raithby, Ronald Snaith, Dietmar Stalke, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

A Ca₂ complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl₂ with [Ox₂Ca(HMPA)₂] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt²⁺ with DNA bases. (Figure Presented.)

Original language	English
Pages (from-to)	1648-1650
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	12
DOIs	https://doi.org/10.1002/anie.199116481
Publication status	Published - Dec 1991

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "The Reaction of PtCl2 with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion",

abstract = "A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)",

author = "Davidson, {Matthew G.} and Raithby, {Paul R.} and Ronald Snaith and Dietmar Stalke and Wright, {Dominic S.}",

year = "1991",

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AU - Davidson, Matthew G.

AU - Raithby, Paul R.

AU - Snaith, Ronald

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1991/12

Y1 - 1991/12

N2 - A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)

AB - A Ca2 complex cation combines with the Ca‐Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases. (Figure Presented.)

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The Reaction of PtCl₂ with an N,S,O‐Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

Abstract

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