The reaction of NO+ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H3Os4(CO) 12(μ2-NO)] and [HRu4N(CO) 11P(OME)3]

Dario Braga; Brian F.G. Johnson; Jack Lewis; Julian M. Mace; Mary McPartlin; José Puga; William J.H. Nelson; Paul R. Raithby; Kenton H. Whitmire

doi:10.1039/C39820001081

The reaction of NO⁺ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H₃Os₄(CO) ₁₂(μ₂-NO)] and [HRu₄N(CO) ₁₁P(OME)₃]

Dario Braga
, Brian F.G. Johnson
, Jack Lewis
, Julian M. Mace
, Mary McPartlin
, José Puga
, William J.H. Nelson
, Paul R. Raithby
, Kenton H. Whitmire

London Metropolitan University
University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [H₃Os₄(CO)₁₂]^- with NOBF₄ in CH₂Cl₂ gives the nitrosyl cluster [H₃Os₄(CO)₁₂(μ-NO)] in which the NO ligand has been shown by X-ray analysis to adopt a unique bonding mode bridging the wing-tips of a butterfly arrangement of metal atoms; the analogous reaction of [H₃Ru₄(CO)₁₂]^- with NOBF₄ gives instead the nitrido-cluster [HRu₄N(CO)₁₂] in low yield, whose formulation has been confirmed by an X-ray analysis of the derivative [HRu₄N(CO)₁₁P(OMe)₃].

Original language	English
Pages (from-to)	1081-1083
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39820001081
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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Braga, D., Johnson, B. F. G., Lewis, J., Mace, J. M., McPartlin, M., Puga, J., Nelson, W. J. H., Raithby, P. R., & Whitmire, K. H. (1982). The reaction of NO⁺ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H₃Os₄(CO) ₁₂(μ₂-NO)] and [HRu₄N(CO) ₁₁P(OME)₃]. Journal of the Chemical Society, Chemical Communications, (18), 1081-1083. https://doi.org/10.1039/C39820001081

Braga, D, Johnson, BFG, Lewis, J, Mace, JM, McPartlin, M, Puga, J, Nelson, WJH, Raithby, PR & Whitmire, KH 1982, 'The reaction of NO⁺ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H₃Os₄(CO) ₁₂(μ₂-NO)] and [HRu₄N(CO) ₁₁P(OME)₃]', Journal of the Chemical Society, Chemical Communications, no. 18, pp. 1081-1083. https://doi.org/10.1039/C39820001081

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title = "The reaction of NO+ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H3Os4(CO) 12(μ2-NO)] and [HRu4N(CO) 11P(OME)3]",

abstract = "Reaction of [H3Os4(CO)12]- with NOBF4 in CH2Cl2 gives the nitrosyl cluster [H3Os4(CO)12(μ-NO)] in which the NO ligand has been shown by X-ray analysis to adopt a unique bonding mode bridging the wing-tips of a butterfly arrangement of metal atoms; the analogous reaction of [H3Ru4(CO)12]- with NOBF4 gives instead the nitrido-cluster [HRu4N(CO)12] in low yield, whose formulation has been confirmed by an X-ray analysis of the derivative [HRu4N(CO)11P(OMe)3].",

author = "Dario Braga and Johnson, \{Brian F.G.\} and Jack Lewis and Mace, \{Julian M.\} and Mary McPartlin and Jos{\'e} Puga and Nelson, \{William J.H.\} and Raithby, \{Paul R.\} and Whitmire, \{Kenton H.\}",

year = "1982",

doi = "10.1039/C39820001081",

language = "English",

pages = "1081--1083",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "18",

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TY - JOUR

T1 - The reaction of NO+ with some anions of osmium and ruthenium

T2 - Synthesis and x-ray characterization of [H3Os4(CO) 12(μ2-NO)] and [HRu4N(CO) 11P(OME)3]

AU - Braga, Dario

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Mace, Julian M.

AU - McPartlin, Mary

AU - Puga, José

AU - Nelson, William J.H.

AU - Raithby, Paul R.

AU - Whitmire, Kenton H.

PY - 1982

Y1 - 1982

N2 - Reaction of [H3Os4(CO)12]- with NOBF4 in CH2Cl2 gives the nitrosyl cluster [H3Os4(CO)12(μ-NO)] in which the NO ligand has been shown by X-ray analysis to adopt a unique bonding mode bridging the wing-tips of a butterfly arrangement of metal atoms; the analogous reaction of [H3Ru4(CO)12]- with NOBF4 gives instead the nitrido-cluster [HRu4N(CO)12] in low yield, whose formulation has been confirmed by an X-ray analysis of the derivative [HRu4N(CO)11P(OMe)3].

AB - Reaction of [H3Os4(CO)12]- with NOBF4 in CH2Cl2 gives the nitrosyl cluster [H3Os4(CO)12(μ-NO)] in which the NO ligand has been shown by X-ray analysis to adopt a unique bonding mode bridging the wing-tips of a butterfly arrangement of metal atoms; the analogous reaction of [H3Ru4(CO)12]- with NOBF4 gives instead the nitrido-cluster [HRu4N(CO)12] in low yield, whose formulation has been confirmed by an X-ray analysis of the derivative [HRu4N(CO)11P(OMe)3].

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U2 - 10.1039/C39820001081

DO - 10.1039/C39820001081

M3 - Article

AN - SCOPUS:37049097251

SN - 0022-4936

SP - 1081

EP - 1083

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 18

ER -

The reaction of NO⁺ with some anions of osmium and ruthenium: Synthesis and x-ray characterization of [H₃Os₄(CO) ₁₂(μ₂-NO)] and [HRu₄N(CO) ₁₁P(OME)₃]

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