The preparation and structure of the tetranuclear ruthenium cluster [Ru4(CO)10(μ2-Cl)2(μ3-OEt)2]

Brian F. G. Johnson; Jack Lewis; Julian M. Mace; Paul R. Raithby; Maria D. Vargas

doi:10.1016/0022-328X(87)80313-3

The preparation and structure of the tetranuclear ruthenium cluster [Ru₄(CO)₁₀(μ₂-Cl)₂(μ₃-OEt)₂]

Brian F. G. Johnson, Jack Lewis, Julian M. Mace, Paul R. Raithby, Maria D. Vargas

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The tetranuclear ruthenium cluster [Ru₄(CO)₁₀Cl₂(OEt)₂] has been prepared in low yield by the reaction of [Ru₃(CO)₁₂] with [N(PPh₃)₂]Cl in refluxing EtOH, followed by oxidation with either [NO][BF₄] or Ag[ClO₄]. A single-crystal X-ray analysis of the complex shows that the four metal atoms adopt a planar geometry with one ruthenium bonded by two μ₂-Cl ligands and two μ₃-OEt ligands to a trinuclear fragment. This complex crystallises in the monoclinic space group I2/c, with a 14.458(3), b 22.073(6), c 15.302(4) Å, β 99.54(2)°, Z = 8; 3113 observed data with F > 3σ(F) were refined by blocked full-matrix least squares to R = 0.031, R_w = 0.034.

Original language	English
Pages (from-to)	409-416
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	321
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(87)80313-3
Publication status	Published - 10 Apr 1987

Funding

J.M.M. is grateful to British Petroleum and Corpus Christi College, Cambridge for financial support. M.D.V. is grateful to Sidney Sussex College, Cambridge for a Research Fellowship.

Funders	Funder number
Corpus Christi College, University of Cambridge
Sidney Sussex College, University of Cambridge

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(87)80313-3

Cite this

@article{2271c409b50144108807d8dc5bd11849,

title = "The preparation and structure of the tetranuclear ruthenium cluster [Ru4(CO)10(μ2-Cl)2(μ3-OEt)2]",

abstract = "The tetranuclear ruthenium cluster [Ru4(CO)10Cl2(OEt)2] has been prepared in low yield by the reaction of [Ru3(CO)12] with [N(PPh3)2]Cl in refluxing EtOH, followed by oxidation with either [NO][BF4] or Ag[ClO4]. A single-crystal X-ray analysis of the complex shows that the four metal atoms adopt a planar geometry with one ruthenium bonded by two μ2-Cl ligands and two μ3-OEt ligands to a trinuclear fragment. This complex crystallises in the monoclinic space group I2/c, with a 14.458(3), b 22.073(6), c 15.302(4) {\AA}, β 99.54(2)°, Z = 8; 3113 observed data with F > 3σ(F) were refined by blocked full-matrix least squares to R = 0.031, Rw = 0.034.",

author = "Johnson, \{Brian F. G.\} and Jack Lewis and Mace, \{Julian M.\} and Raithby, \{Paul R.\} and Vargas, \{Maria D.\}",

year = "1987",

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doi = "10.1016/0022-328X(87)80313-3",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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T1 - The preparation and structure of the tetranuclear ruthenium cluster [Ru4(CO)10(μ2-Cl)2(μ3-OEt)2]

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - Mace, Julian M.

AU - Raithby, Paul R.

AU - Vargas, Maria D.

PY - 1987/4/10

Y1 - 1987/4/10

N2 - The tetranuclear ruthenium cluster [Ru4(CO)10Cl2(OEt)2] has been prepared in low yield by the reaction of [Ru3(CO)12] with [N(PPh3)2]Cl in refluxing EtOH, followed by oxidation with either [NO][BF4] or Ag[ClO4]. A single-crystal X-ray analysis of the complex shows that the four metal atoms adopt a planar geometry with one ruthenium bonded by two μ2-Cl ligands and two μ3-OEt ligands to a trinuclear fragment. This complex crystallises in the monoclinic space group I2/c, with a 14.458(3), b 22.073(6), c 15.302(4) Å, β 99.54(2)°, Z = 8; 3113 observed data with F > 3σ(F) were refined by blocked full-matrix least squares to R = 0.031, Rw = 0.034.

AB - The tetranuclear ruthenium cluster [Ru4(CO)10Cl2(OEt)2] has been prepared in low yield by the reaction of [Ru3(CO)12] with [N(PPh3)2]Cl in refluxing EtOH, followed by oxidation with either [NO][BF4] or Ag[ClO4]. A single-crystal X-ray analysis of the complex shows that the four metal atoms adopt a planar geometry with one ruthenium bonded by two μ2-Cl ligands and two μ3-OEt ligands to a trinuclear fragment. This complex crystallises in the monoclinic space group I2/c, with a 14.458(3), b 22.073(6), c 15.302(4) Å, β 99.54(2)°, Z = 8; 3113 observed data with F > 3σ(F) were refined by blocked full-matrix least squares to R = 0.031, Rw = 0.034.

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