The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction

Edwin C. Constable; Fatima K. Khan; Jack Lewis; Michael C. Liptrot; Paul R. Raithby

doi:10.1039/DT9850000333

The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction

Edwin C. Constable, Fatima K. Khan, Jack Lewis, Michael C. Liptrot, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The complex [SnMe₂L]Cl₂ [L = 6,6″-bis(α-methylhydrazino)-4′-phenyl-2,2′:6′, 2″-terpyridine] is involved in the dimethyltin(IV) mediated transient template condensation of L with glyoxal; the complex has been structurally characterised, and shown to possess a pentagonal-bipyramidal geometry about the metal. The transient template effect is seen to originate in a reduction in the hole size of the N₅ donor set on passing from the open-chain ligand to the macrocycle.

Original language	English
Pages (from-to)	333-335
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9850000333
Publication status	Published - 31 Dec 1985

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1039/DT9850000333

Cite this

The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction. / Constable, Edwin C.; Khan, Fatima K.; Lewis, Jack et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 2, 31.12.1985, p. 333-335.

Research output: Contribution to journal › Article › peer-review

@article{fe60fa12144b4006a58fda8e70538a65,

title = "The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction",

abstract = "The complex [SnMe2L]Cl2 [L = 6,6″-bis(α-methylhydrazino)-4′-phenyl-2,2′:6′, 2″-terpyridine] is involved in the dimethyltin(IV) mediated transient template condensation of L with glyoxal; the complex has been structurally characterised, and shown to possess a pentagonal-bipyramidal geometry about the metal. The transient template effect is seen to originate in a reduction in the hole size of the N5 donor set on passing from the open-chain ligand to the macrocycle.",

author = "Constable, {Edwin C.} and Khan, {Fatima K.} and Jack Lewis and Liptrot, {Michael C.} and Raithby, {Paul R.}",

year = "1985",

month = dec,

day = "31",

doi = "10.1039/DT9850000333",

language = "English",

pages = "333--335",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction

AU - Constable, Edwin C.

AU - Khan, Fatima K.

AU - Lewis, Jack

AU - Liptrot, Michael C.

AU - Raithby, Paul R.

PY - 1985/12/31

Y1 - 1985/12/31

N2 - The complex [SnMe2L]Cl2 [L = 6,6″-bis(α-methylhydrazino)-4′-phenyl-2,2′:6′, 2″-terpyridine] is involved in the dimethyltin(IV) mediated transient template condensation of L with glyoxal; the complex has been structurally characterised, and shown to possess a pentagonal-bipyramidal geometry about the metal. The transient template effect is seen to originate in a reduction in the hole size of the N5 donor set on passing from the open-chain ligand to the macrocycle.

AB - The complex [SnMe2L]Cl2 [L = 6,6″-bis(α-methylhydrazino)-4′-phenyl-2,2′:6′, 2″-terpyridine] is involved in the dimethyltin(IV) mediated transient template condensation of L with glyoxal; the complex has been structurally characterised, and shown to possess a pentagonal-bipyramidal geometry about the metal. The transient template effect is seen to originate in a reduction in the hole size of the N5 donor set on passing from the open-chain ligand to the macrocycle.

UR - http://www.scopus.com/inward/record.url?scp=37049103507&partnerID=8YFLogxK

U2 - 10.1039/DT9850000333

DO - 10.1039/DT9850000333

M3 - Article

AN - SCOPUS:37049103507

SN - 1472-7773

SP - 333

EP - 335

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 2

ER -

The preparation and co-ordination chemistry of 2,2′:6′,2″-terpyridine macrocycles. Part 4. Structural characterisation of an intermediate in a transient template reaction

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this