The potential of silicon-based ligands in metal-organic frameworks

Robert P. Davies, Askhat Jumabekov, Robert J. Less, Paul D. Lickiss, Karen Robertson, Karl G. Sandeman, Andrew J P White

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This paper presents a description of the synthetic procedures to two silicon-based ligands and to two new metal-organic frameworks (MOFs) derived from these ligands, as well as the results of magnetic measurements on the MOFs. It was found that the new Mn(II) and Co(II) MOFs behave as paramagnets at low temperatures, and one of the compounds (3) experiences first order transition due to a (possible) spin crossover phenomenon.

Original languageEnglish
Title of host publicationNanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Pages103-106
Number of pages4
Volume2
Publication statusPublished - 2010
EventNanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 - Anaheim, CA, USA United States
Duration: 21 Jun 201024 Jun 2010

Conference

ConferenceNanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
CountryUSA United States
CityAnaheim, CA
Period21/06/1024/06/10

Keywords

  • Magnetism
  • Metal-organic frameworks
  • Silicon-based ligands

ASJC Scopus subject areas

  • Hardware and Architecture
  • Electrical and Electronic Engineering

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