The potential of silicon-based ligands in metal-organic frameworks

Robert P. Davies; Askhat Jumabekov; Robert J. Less; Paul D. Lickiss; Karen Robertson; Karl G. Sandeman; Andrew J P White

The potential of silicon-based ligands in metal-organic frameworks

Robert P. Davies, Askhat Jumabekov, Robert J. Less, Paul D. Lickiss, Karen Robertson, Karl G. Sandeman, Andrew J P White

Department of Chemistry

Imperial College London

Research output: Chapter or section in a book/report/conference proceeding › Chapter in a published conference proceeding

Abstract

This paper presents a description of the synthetic procedures to two silicon-based ligands and to two new metal-organic frameworks (MOFs) derived from these ligands, as well as the results of magnetic measurements on the MOFs. It was found that the new Mn(II) and Co(II) MOFs behave as paramagnets at low temperatures, and one of the compounds (3) experiences first order transition due to a (possible) spin crossover phenomenon.

Original language	English
Title of host publication	Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Pages	103-106
Number of pages	4
Volume	2
Publication status	Published - 2010
Event	Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 - Anaheim, CA, USA United States Duration: 21 Jun 2010 → 24 Jun 2010

Conference

Conference	Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Country/Territory	USA United States
City	Anaheim, CA
Period	21/06/10 → 24/06/10

Keywords

Magnetism
Metal-organic frameworks
Silicon-based ligands

ASJC Scopus subject areas

Hardware and Architecture
Electrical and Electronic Engineering

Cite this

Davies, R. P., Jumabekov, A., Less, R. J., Lickiss, P. D., Robertson, K., Sandeman, K. G., & White, A. J. P. (2010). The potential of silicon-based ligands in metal-organic frameworks. In Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 (Vol. 2, pp. 103-106)

The potential of silicon-based ligands in metal-organic frameworks. / Davies, Robert P.; Jumabekov, Askhat; Less, Robert J. et al.
Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Vol. 2 2010. p. 103-106.

Research output: Chapter or section in a book/report/conference proceeding › Chapter in a published conference proceeding

Davies, RP, Jumabekov, A, Less, RJ, Lickiss, PD, Robertson, K, Sandeman, KG & White, AJP 2010, The potential of silicon-based ligands in metal-organic frameworks. in Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. vol. 2, pp. 103-106, Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010, Anaheim, CA, USA United States, 21/06/10.

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abstract = "This paper presents a description of the synthetic procedures to two silicon-based ligands and to two new metal-organic frameworks (MOFs) derived from these ligands, as well as the results of magnetic measurements on the MOFs. It was found that the new Mn(II) and Co(II) MOFs behave as paramagnets at low temperatures, and one of the compounds (3) experiences first order transition due to a (possible) spin crossover phenomenon.",

keywords = "Magnetism, Metal-organic frameworks, Silicon-based ligands",

author = "Davies, {Robert P.} and Askhat Jumabekov and Less, {Robert J.} and Lickiss, {Paul D.} and Karen Robertson and Sandeman, {Karl G.} and White, {Andrew J P}",

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T1 - The potential of silicon-based ligands in metal-organic frameworks

AU - Davies, Robert P.

AU - Jumabekov, Askhat

AU - Less, Robert J.

AU - Lickiss, Paul D.

AU - Robertson, Karen

AU - Sandeman, Karl G.

AU - White, Andrew J P

PY - 2010

Y1 - 2010

N2 - This paper presents a description of the synthetic procedures to two silicon-based ligands and to two new metal-organic frameworks (MOFs) derived from these ligands, as well as the results of magnetic measurements on the MOFs. It was found that the new Mn(II) and Co(II) MOFs behave as paramagnets at low temperatures, and one of the compounds (3) experiences first order transition due to a (possible) spin crossover phenomenon.

AB - This paper presents a description of the synthetic procedures to two silicon-based ligands and to two new metal-organic frameworks (MOFs) derived from these ligands, as well as the results of magnetic measurements on the MOFs. It was found that the new Mn(II) and Co(II) MOFs behave as paramagnets at low temperatures, and one of the compounds (3) experiences first order transition due to a (possible) spin crossover phenomenon.

KW - Magnetism

KW - Metal-organic frameworks

KW - Silicon-based ligands

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M3 - Chapter in a published conference proceeding

AN - SCOPUS:78049430926

SN - 9781439834022

VL - 2

SP - 103

EP - 106

BT - Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010

T2 - Nanotechnology 2010: Electronics, Devices, Fabrication, MEMS, Fluidics and Computational - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010

Y2 - 21 June 2010 through 24 June 2010

ER -

The potential of silicon-based ligands in metal-organic frameworks

Abstract

Conference

Keywords

ASJC Scopus subject areas

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