The photochemistry of M3(CO)12 (M = Ru, Os) with pyrazole and its substituted derivatives

Nicholas E. Leadbeater, Jack Lewis, Paul R. Raithby, Gregory P. Ward

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The photochemistry of M3(CO)12 [M = Ru (1a), Os (1b)] with pyrazole, 3,5-dimethylpyrazole, and 3,5-diphenylpyrazole is documented. With 1a, photolysis with pyrazole leads to the substitution product HRu3(CO)10(C3H3N2) (2a). In the case of 1b, the initial product is the ortho-metallated species HOs3(CO)10(C3H3N2) (3b), heating of which yields HOs3(CO)10(C3H3N2) (2b). Photolysis of 1a and 1b with 3,5-dimethylpyrazole yields HRu3(CO)10(C3HMe2N2) (4a) and HOs3(CO)10(C3HMe2N2) (4b), respectively. The molecular structure of 4b has been determined by X-ray crystallography. There is no reaction on photolysis of 1a and 1b with 3,5-diphenylpyrazole.

Original languageEnglish
Pages (from-to)1479-1483
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Issue number10
DOIs
Publication statusPublished - Oct 1998

Keywords

  • Clusters
  • Nitrogen heterocycles
  • Osmium
  • Photochemistry
  • Ruthenium

ASJC Scopus subject areas

  • Inorganic Chemistry

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