The photochemical generation and some exploratory reactions of the novel di-hydrido tri-ruthenium cluster (H2Ru3(CO)10)

Nicholas E. Leadbeater; Jack Lewis; Paul R. Raithby

doi:10.1016/S0022-328X(97)00231-3

The photochemical generation and some exploratory reactions of the novel di-hydrido tri-ruthenium cluster (H₂Ru₃(CO)₁₀)

Nicholas E. Leadbeater, Jack Lewis, Paul R. Raithby

Durham University

Research output: Contribution to journal › Article › peer-review

21 Citations (SciVal)

Abstract

The title compound, H₂Ru₃(CO)₁₀ 2, is synthesised by the photolysis of Ru₃(CO)₁₂ 4 under an atmosphere of di-hydrogen, and has been shown by IR and NMR to be structurally analogous to H₂OS₃(CO)₁₀ 1. The reaction of 2 with triphenylphosphine and phenylacetylene leads to the formation of the simple adducts H₂Ru₃(CO)₁₀PPh₃ 6 and HRu₃(CO)₁₀(μ₃-η₂-C₂Ph) 7, respectively. The reaction of 2 with cyclohexa-1,3-diene at room temperature results in the formation of the mononuclear complex Ru(CO)₃(C₆H₈) 9.

Original language	English
Pages (from-to)	251-253
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	543
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(97)00231-3
Publication status	Published - 30 Sept 1997

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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abstract = "The title compound, H2Ru3(CO)10 2, is synthesised by the photolysis of Ru3(CO)12 4 under an atmosphere of di-hydrogen, and has been shown by IR and NMR to be structurally analogous to H2OS3(CO)10 1. The reaction of 2 with triphenylphosphine and phenylacetylene leads to the formation of the simple adducts H2Ru3(CO)10PPh3 6 and HRu3(CO)10(μ3-η2-C2Ph) 7, respectively. The reaction of 2 with cyclohexa-1,3-diene at room temperature results in the formation of the mononuclear complex Ru(CO)3(C6H8) 9.",

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AU - Raithby, Paul R.

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AB - The title compound, H2Ru3(CO)10 2, is synthesised by the photolysis of Ru3(CO)12 4 under an atmosphere of di-hydrogen, and has been shown by IR and NMR to be structurally analogous to H2OS3(CO)10 1. The reaction of 2 with triphenylphosphine and phenylacetylene leads to the formation of the simple adducts H2Ru3(CO)10PPh3 6 and HRu3(CO)10(μ3-η2-C2Ph) 7, respectively. The reaction of 2 with cyclohexa-1,3-diene at room temperature results in the formation of the mononuclear complex Ru(CO)3(C6H8) 9.

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The photochemical generation and some exploratory reactions of the novel di-hydrido tri-ruthenium cluster (H₂Ru₃(CO)₁₀)

Abstract

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