The peroxo-group as a doubly bidentate bridging ligand in five-co-ordinate lanthanide complexes

Donald C. Bradley; Joginder S. Ghotra; F. Alan Hart; Michael B. Hursthouse; Paul R. Raithby

doi:10.1039/C39740000040

The peroxo-group as a doubly bidentate bridging ligand in five-co-ordinate lanthanide complexes

Donald C. Bradley, Joginder S. Ghotra, F. Alan Hart, Michael B. Hursthouse, Paul R. Raithby

Queen Mary University, London

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of OPPh₃ with M{N(SiMe₃)₂} ₃(M = a lanthanide) yields complexes M₂O ₂{N(SiMe₃)₂}₄(OPPh₃) ₂ which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

Original language	English
Pages (from-to)	40-41
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39740000040
Publication status	Published - 31 Dec 1974

ASJC Scopus subject areas

Molecular Medicine

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title = "The peroxo-group as a doubly bidentate bridging ligand in five-co-ordinate lanthanide complexes",

abstract = "Reaction of OPPh3 with M\{N(SiMe3)2\} 3(M = a lanthanide) yields complexes M2O 2\{N(SiMe3)2\}4(OPPh3) 2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.",

author = "Bradley, \{Donald C.\} and Ghotra, \{Joginder S.\} and Hart, \{F. Alan\} and Hursthouse, \{Michael B.\} and Raithby, \{Paul R.\}",

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doi = "10.1039/C39740000040",

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AU - Bradley, Donald C.

AU - Ghotra, Joginder S.

AU - Hart, F. Alan

AU - Hursthouse, Michael B.

AU - Raithby, Paul R.

PY - 1974/12/31

Y1 - 1974/12/31

N2 - Reaction of OPPh3 with M{N(SiMe3)2} 3(M = a lanthanide) yields complexes M2O 2{N(SiMe3)2}4(OPPh3) 2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

AB - Reaction of OPPh3 with M{N(SiMe3)2} 3(M = a lanthanide) yields complexes M2O 2{N(SiMe3)2}4(OPPh3) 2 which contain a doubly bidentate peroxo-group and 5-co-ordinate lanthanide ions.

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DO - 10.1039/C39740000040

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

The peroxo-group as a doubly bidentate bridging ligand in five-co-ordinate lanthanide complexes

Abstract

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