The observation of a Pb-Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph3Pb-Li·(pmdeta) complex [pmdeta = (Me2NCH2CH2)2NMe]

David R. Armstrong; Matthew G. Davidson; David Moncrieff; Dietmar Stalke; Dominic S. Wright

doi:10.1039/C39920001413

The observation of a Pb-Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph₃Pb-Li·(pmdeta) complex [pmdeta = (Me₂NCH₂CH₂)₂NMe]

David R. Armstrong, Matthew G. Davidson, David Moncrieff, Dietmar Stalke, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound has been synthesised by the cleavage reaction of Ph ₃Pb-PbPh₃ with BuⁿLi and has been shown to have a monomeric Pb-Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.

Original language	English
Pages (from-to)	1413-1415
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39920001413
Publication status	Published - 1992

ASJC Scopus subject areas

Molecular Medicine

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Armstrong, D. R., Davidson, M. G., Moncrieff, D., Stalke, D., & Wright, D. S. (1992). The observation of a Pb-Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph₃Pb-Li·(pmdeta) complex [pmdeta = (Me₂NCH₂CH₂)₂NMe]. Journal of the Chemical Society, Chemical Communications, (19), 1413-1415. https://doi.org/10.1039/C39920001413

The observation of a Pb-Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph₃Pb-Li·(pmdeta) complex [pmdeta = (Me₂NCH₂CH₂)₂NMe]. / Armstrong, David R.; Davidson, Matthew G.; Moncrieff, David et al.
In: Journal of the Chemical Society, Chemical Communications, No. 19, 1992, p. 1413-1415.

Research output: Contribution to journal › Article › peer-review

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abstract = "The title compound has been synthesised by the cleavage reaction of Ph 3Pb-PbPh3 with BunLi and has been shown to have a monomeric Pb-Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.",

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AU - Davidson, Matthew G.

AU - Moncrieff, David

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1992

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AB - The title compound has been synthesised by the cleavage reaction of Ph 3Pb-PbPh3 with BunLi and has been shown to have a monomeric Pb-Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.

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The observation of a Pb-Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph₃Pb-Li·(pmdeta) complex [pmdeta = (Me₂NCH₂CH₂)₂NMe]

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