The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η5-C5H 5)Tl(μ-C5H5)Tl(μ5-C 5H5)]-[Li(12-crown-4)2] +·thf

David R. Armstrong; Andrew J. Edwards; David Moncrieff; Michael A. Paver; Paul R. Raithby; Moira Ann Rennie; Christopher A. Russell; Dominic S. Wright

doi:10.1039/C39950000927

The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η⁵-C₅H ₅)Tl(μ-C₅H₅)Tl(μ⁵-C ₅H₅)]^-[Li(12-crown-4)₂] ⁺·thf

David R. Armstrong, Andrew J. Edwards, David Moncrieff, Michael A. Paver, Paul R. Raithby, Moira Ann Rennie, Christopher A. Russell, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of (C₅H₅)Li with (η⁵-C ₅H₅)Tl (1.2 equiv.) in the presence of 12-crown-4 (2 equiv.) produces the ion-separated complex [(η⁵-C ₅H₅)Tl(μ-C₅H₅) Tl(μ⁵-C₅H₅)]^-[Li(12-crown-4) ₂]₊·thf 1 which contains the first homometallic main group metal triple-decker sandwich as the anion; this anion can be viewed as the first homologue of the thallocene anion [(η⁵-C ₅H₅)₂Tl]^- and is a molecular segment of the polymeric structure of [(η⁵-C₅H ₅)Tl]_∞.

Original language	English
Pages (from-to)	927-928
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1995
Issue number	9
DOIs	https://doi.org/10.1039/C39950000927
Publication status	Published - 31 Dec 1995

ASJC Scopus subject areas

Molecular Medicine

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Armstrong, D. R., Edwards, A. J., Moncrieff, D., Paver, M. A., Raithby, P. R., Rennie, M. A., Russell, C. A., & Wright, D. S. (1995). The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η⁵-C₅H ₅)Tl(μ-C₅H₅)Tl(μ⁵-C ₅H₅)]^-[Li(12-crown-4)₂] ⁺·thf. Journal of the Chemical Society, Chemical Communications, 1995(9), 927-928. https://doi.org/10.1039/C39950000927

The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η⁵-C₅H ₅)Tl(μ-C₅H₅)Tl(μ⁵-C ₅H₅)]^-[Li(12-crown-4)₂] ⁺·thf. / Armstrong, David R.; Edwards, Andrew J.; Moncrieff, David et al.
In: Journal of the Chemical Society, Chemical Communications, Vol. 1995, No. 9, 31.12.1995, p. 927-928.

Research output: Contribution to journal › Article › peer-review

Armstrong, DR, Edwards, AJ, Moncrieff, D, Paver, MA, Raithby, PR, Rennie, MA, Russell, CA & Wright, DS 1995, 'The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η⁵-C₅H ₅)Tl(μ-C₅H₅)Tl(μ⁵-C ₅H₅)]^-[Li(12-crown-4)₂] ⁺·thf', Journal of the Chemical Society, Chemical Communications, vol. 1995, no. 9, pp. 927-928. https://doi.org/10.1039/C39950000927

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title = "The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η5-C5H 5)Tl(μ-C5H5)Tl(μ5-C 5H5)]-[Li(12-crown-4)2] +·thf",

abstract = "Reaction of (C5H5)Li with (η5-C 5H5)Tl (1.2 equiv.) in the presence of 12-crown-4 (2 equiv.) produces the ion-separated complex [(η5-C 5H5)Tl(μ-C5H5) Tl(μ5-C5H5)]-[Li(12-crown-4) 2]+·thf 1 which contains the first homometallic main group metal triple-decker sandwich as the anion; this anion can be viewed as the first homologue of the thallocene anion [(η5-C 5H5)2Tl]- and is a molecular segment of the polymeric structure of [(η5-C5H 5)Tl]∞.",

author = "Armstrong, {David R.} and Edwards, {Andrew J.} and David Moncrieff and Paver, {Michael A.} and Raithby, {Paul R.} and Rennie, {Moira Ann} and Russell, {Christopher A.} and Wright, {Dominic S.}",

year = "1995",

month = dec,

day = "31",

doi = "10.1039/C39950000927",

language = "English",

volume = "1995",

pages = "927--928",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η5-C5H 5)Tl(μ-C5H5)Tl(μ5-C 5H5)]-[Li(12-crown-4)2] +·thf

AU - Armstrong, David R.

AU - Edwards, Andrew J.

AU - Moncrieff, David

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Rennie, Moira Ann

AU - Russell, Christopher A.

AU - Wright, Dominic S.

PY - 1995/12/31

Y1 - 1995/12/31

N2 - Reaction of (C5H5)Li with (η5-C 5H5)Tl (1.2 equiv.) in the presence of 12-crown-4 (2 equiv.) produces the ion-separated complex [(η5-C 5H5)Tl(μ-C5H5) Tl(μ5-C5H5)]-[Li(12-crown-4) 2]+·thf 1 which contains the first homometallic main group metal triple-decker sandwich as the anion; this anion can be viewed as the first homologue of the thallocene anion [(η5-C 5H5)2Tl]- and is a molecular segment of the polymeric structure of [(η5-C5H 5)Tl]∞.

AB - Reaction of (C5H5)Li with (η5-C 5H5)Tl (1.2 equiv.) in the presence of 12-crown-4 (2 equiv.) produces the ion-separated complex [(η5-C 5H5)Tl(μ-C5H5) Tl(μ5-C5H5)]-[Li(12-crown-4) 2]+·thf 1 which contains the first homometallic main group metal triple-decker sandwich as the anion; this anion can be viewed as the first homologue of the thallocene anion [(η5-C 5H5)2Tl]- and is a molecular segment of the polymeric structure of [(η5-C5H 5)Tl]∞.

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U2 - 10.1039/C39950000927

DO - 10.1039/C39950000927

M3 - Article

AN - SCOPUS:37049078236

SN - 0022-4936

VL - 1995

SP - 927

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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ER -

The next homologue of the bis(cyclopentadienyl)thallate anion; synthesis and X-ray structure determination of [(η⁵-C₅H ₅)Tl(μ-C₅H₅)Tl(μ⁵-C ₅H₅)]^-[Li(12-crown-4)₂] ⁺·thf

Abstract

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