The molecular structure of (PSH+)(nido-7,8-C2B9H12 -) determined by neutron diffraction (PS = Proton Sponge, 1,8-Bis(dimethylamino)naphthalene)

M. A. Fox; A. E. Goeta; J. A.K. Howard; A. K. Hughes; A. L. Johnson; D. A. Keen; K. Wade; C. C. Wilson

doi:10.1021/ic000961e

The molecular structure of (PSH⁺)(nido-7,8-C₂B₉H₁₂ ^-) determined by neutron diffraction (PS = Proton Sponge, 1,8-Bis(dimethylamino)naphthalene)

M. A. Fox, A. E. Goeta, J. A.K. Howard, A. K. Hughes, A. L. Johnson, D. A. Keen, K. Wade, C. C. Wilson

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Abstract

A neutron diffraction study of the salt (PSH⁺)(nido-7,8-C₂B₉H₁₂ ^-) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.

Original language	English
Pages (from-to)	173-175
Number of pages	3
Journal	Inorganic Chemistry
Volume	40
Issue number	1
DOIs	https://doi.org/10.1021/ic000961e
Publication status	Published - 1 Jan 2001

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic000961e

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abstract = "A neutron diffraction study of the salt (PSH+)(nido-7,8-C2B9H12 -) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.",

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AU - Fox, M. A.

AU - Goeta, A. E.

AU - Howard, J. A.K.

AU - Hughes, A. K.

AU - Johnson, A. L.

AU - Keen, D. A.

AU - Wade, K.

AU - Wilson, C. C.

PY - 2001/1/1

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N2 - A neutron diffraction study of the salt (PSH+)(nido-7,8-C2B9H12 -) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.

AB - A neutron diffraction study of the salt (PSH+)(nido-7,8-C2B9H12 -) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.

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The molecular structure of (PSH⁺)(nido-7,8-C₂B₉H₁₂ ^-) determined by neutron diffraction (PS = Proton Sponge, 1,8-Bis(dimethylamino)naphthalene)

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