The metallation of imino(triphenyl)phosphorane by ethylmagnesium chloride: The synthesis, isolation and X-ray structure of [Ph3P=NMgCl · O=P(NMe2)3]2

Andrei S. Batsanov; Philip D. Bolton; Royston C.B. Copley; Matthew G. Davidson; Judith A.K. Howard; Christian Lustig; Richard D. Price

doi:10.1016/S0022-328X(97)00550-0

The metallation of imino(triphenyl)phosphorane by ethylmagnesium chloride: The synthesis, isolation and X-ray structure of [Ph₃P=NMgCl · O=P(NMe₂)₃]₂

Andrei S. Batsanov, Philip D. Bolton, Royston C.B. Copley, Matthew G. Davidson, Judith A.K. Howard, Christian Lustig, Richard D. Price

Durham University

Research output: Contribution to journal › Article › peer-review

16 Citations (SciVal)

Abstract

Imino(triphenyl)phosphorane, Ph₃P=NH 1a, is metallated by ethylmagnesium chloride to give the N-magnesioiminophosphorane complex [Ph₃P=NMgCl · O=P(NMe₂)₃]₂ 4, whose X-ray structure has been determined.

Original language	English
Pages (from-to)	445-448
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	550
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(97)00550-0
Publication status	Published - 15 Jan 1998

Keywords

Grignard reagent
Iminophosphorane
Organomagnesium
X-ray diffraction

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(97)00550-0

Cite this

Batsanov, A. S., Bolton, P. D., Copley, R. C. B., Davidson, M. G., Howard, J. A. K., Lustig, C., & Price, R. D. (1998). The metallation of imino(triphenyl)phosphorane by ethylmagnesium chloride: The synthesis, isolation and X-ray structure of [Ph₃P=NMgCl · O=P(NMe₂)₃]₂. Journal of Organometallic Chemistry, 550(1-2), 445-448. https://doi.org/10.1016/S0022-328X(97)00550-0

The metallation of imino(triphenyl)phosphorane by ethylmagnesium chloride: The synthesis, isolation and X-ray structure of [Ph₃P=NMgCl · O=P(NMe₂)₃]₂. / Batsanov, Andrei S.; Bolton, Philip D.; Copley, Royston C.B. et al.
In: Journal of Organometallic Chemistry, Vol. 550, No. 1-2, 15.01.1998, p. 445-448.

Research output: Contribution to journal › Article › peer-review

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abstract = "Imino(triphenyl)phosphorane, Ph3P=NH 1a, is metallated by ethylmagnesium chloride to give the N-magnesioiminophosphorane complex [Ph3P=NMgCl · O=P(NMe2)3]2 4, whose X-ray structure has been determined.",

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AU - Howard, Judith A.K.

AU - Lustig, Christian

AU - Price, Richard D.

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KW - X-ray diffraction

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