The linking of two acetylide units through a plane of four iron atoms

John E. Davies; Martin J. Mays; Paul R. Raithby; Koshala Sarveswaran

doi:10.1002/anie.199726681

The linking of two acetylide units through a plane of four iron atoms

John E. Davies, Martin J. Mays, Paul R. Raithby, Koshala Sarveswaran

Durham University

Research output: Contribution to journal › Article › peer-review

20 Citations (SciVal)

Abstract

An unprecedented coordiantion mode for a diyne ligand is present in the Fe4 complex 2, which is accessible by thermolysis of the alkyne complex 1 in toluene at 373 K. In 2 the μ4-η2 acetylide ligands on each Fe4 face are linked together by a CC bond through the plane of four metal atoms.

Original language	English
Pages (from-to)	2668-2669
Number of pages	2
Journal	Angewandte Chemie (International Edition in English)
Volume	36
Issue number	23
DOIs	https://doi.org/10.1002/anie.199726681
Publication status	Published - 15 Dec 1997

Keywords

Alkynes
C-C coupling
Clusters
Iron

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199726681

Cite this

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abstract = "An unprecedented coordiantion mode for a diyne ligand is present in the Fe4 complex 2, which is accessible by thermolysis of the alkyne complex 1 in toluene at 373 K. In 2 the μ4-η2 acetylide ligands on each Fe4 face are linked together by a CC bond through the plane of four metal atoms.",

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AU - Raithby, Paul R.

AU - Sarveswaran, Koshala

PY - 1997/12/15

Y1 - 1997/12/15

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AB - An unprecedented coordiantion mode for a diyne ligand is present in the Fe4 complex 2, which is accessible by thermolysis of the alkyne complex 1 in toluene at 373 K. In 2 the μ4-η2 acetylide ligands on each Fe4 face are linked together by a CC bond through the plane of four metal atoms.

KW - Alkynes

KW - C-C coupling

KW - Clusters

KW - Iron

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The linking of two acetylide units through a plane of four iron atoms

Abstract

Keywords

ASJC Scopus subject areas

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