The hydrogen bonded polymer structures of [{Mn(2-mbiH)2·TMEDA}·A- A](∞) [2-mbiH2 = 2-mercaptobenzimidazole; A-A = TMEDA (Me2NCH2CH2NME2) or DABCO (N{CH2CH2}3N)]

Michael A. Beswick; Marta E.G. Mosquera; Julie S. Palmer; Paul R. Raithby; Dominic S. Wright

doi:10.1039/a809066a

The hydrogen bonded polymer structures of [{Mn(2-mbiH)₂·TMEDA}·A- A](∞) [2-mbiH₂ = 2-mercaptobenzimidazole; A-A = TMEDA (Me₂NCH₂CH₂NME₂) or DABCO (N{CH₂CH₂}₃N)]

Michael A. Beswick
, Marta E.G. Mosquera
, Julie S. Palmer
, Paul R. Raithby
, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

7 Citations (SciVal)

Abstract

The reaction of [MnCp₂] with 2-mbiH₂ (1:2 equiv.) in the presence of TMEDA gives [{Mn(2-mbiH)₂·TMEDA}·TMEDA](∞) 1. A similar reaction employing TMEDA and DABCO (1:1 equiv.) yields [{Mn(2- mbiH)₂·TMEDA}·DABCO](∞) 2. In the crystal, both complexes adopt similar polymeric structures in which the bifunctional [Mn(2-mbiH)₂·TMEDA] units are associated by hydrogen bonds to lattice-bound TMEDA or DABCO ligands. The structural motif adopted by both complexes can be regarded as resulting from a fusion of separate helical elements.

Original language	English
Pages (from-to)	1033-1039
Number of pages	7
Journal	New Journal of Chemistry
Volume	23
Issue number	10
DOIs	https://doi.org/10.1039/a809066a
Publication status	Published - 1999

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

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10.1039/a809066a

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@article{2688b603cc29439c87d3de31ce819fd6,

title = "The hydrogen bonded polymer structures of [\{Mn(2-mbiH)2·TMEDA\}·A- A](∞) [2-mbiH2 = 2-mercaptobenzimidazole; A-A = TMEDA (Me2NCH2CH2NME2) or DABCO (N\{CH2CH2\}3N)]",

abstract = "The reaction of [MnCp2] with 2-mbiH2 (1:2 equiv.) in the presence of TMEDA gives [\{Mn(2-mbiH)2·TMEDA\}·TMEDA](∞) 1. A similar reaction employing TMEDA and DABCO (1:1 equiv.) yields [\{Mn(2- mbiH)2·TMEDA\}·DABCO](∞) 2. In the crystal, both complexes adopt similar polymeric structures in which the bifunctional [Mn(2-mbiH)2·TMEDA] units are associated by hydrogen bonds to lattice-bound TMEDA or DABCO ligands. The structural motif adopted by both complexes can be regarded as resulting from a fusion of separate helical elements.",

author = "Beswick, \{Michael A.\} and Mosquera, \{Marta E.G.\} and Palmer, \{Julie S.\} and Raithby, \{Paul R.\} and Wright, \{Dominic S.\}",

year = "1999",

doi = "10.1039/a809066a",

language = "English",

volume = "23",

pages = "1033--1039",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - The hydrogen bonded polymer structures of [{Mn(2-mbiH)2·TMEDA}·A- A](∞) [2-mbiH2 = 2-mercaptobenzimidazole; A-A = TMEDA (Me2NCH2CH2NME2) or DABCO (N{CH2CH2}3N)]

AU - Beswick, Michael A.

AU - Mosquera, Marta E.G.

AU - Palmer, Julie S.

AU - Raithby, Paul R.

AU - Wright, Dominic S.

PY - 1999

Y1 - 1999

N2 - The reaction of [MnCp2] with 2-mbiH2 (1:2 equiv.) in the presence of TMEDA gives [{Mn(2-mbiH)2·TMEDA}·TMEDA](∞) 1. A similar reaction employing TMEDA and DABCO (1:1 equiv.) yields [{Mn(2- mbiH)2·TMEDA}·DABCO](∞) 2. In the crystal, both complexes adopt similar polymeric structures in which the bifunctional [Mn(2-mbiH)2·TMEDA] units are associated by hydrogen bonds to lattice-bound TMEDA or DABCO ligands. The structural motif adopted by both complexes can be regarded as resulting from a fusion of separate helical elements.

AB - The reaction of [MnCp2] with 2-mbiH2 (1:2 equiv.) in the presence of TMEDA gives [{Mn(2-mbiH)2·TMEDA}·TMEDA](∞) 1. A similar reaction employing TMEDA and DABCO (1:1 equiv.) yields [{Mn(2- mbiH)2·TMEDA}·DABCO](∞) 2. In the crystal, both complexes adopt similar polymeric structures in which the bifunctional [Mn(2-mbiH)2·TMEDA] units are associated by hydrogen bonds to lattice-bound TMEDA or DABCO ligands. The structural motif adopted by both complexes can be regarded as resulting from a fusion of separate helical elements.

UR - https://www.scopus.com/pages/publications/0032729423

U2 - 10.1039/a809066a

DO - 10.1039/a809066a

M3 - Article

AN - SCOPUS:0032729423

SN - 1144-0546

VL - 23

SP - 1033

EP - 1039

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

The hydrogen bonded polymer structures of [{Mn(2-mbiH)₂·TMEDA}·A- A](∞) [2-mbiH₂ = 2-mercaptobenzimidazole; A-A = TMEDA (Me₂NCH₂CH₂NME₂) or DABCO (N{CH₂CH₂}₃N)]

Abstract

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