The first synthesis, isolation and X-ray structure of a phosphonium phosphide, (Ph3PMe)+{[C6H2(CF3) 3-2,4,6]2P}-

Matthew G. Davidson; Keith B. Dillon; Judith A.K. Howard; Sarah Lamb; Mark D. Roden

doi:10.1016/S0022-328X(97)00561-5

The first synthesis, isolation and X-ray structure of a phosphonium phosphide, (Ph₃PMe)⁺{[C₆H₂(CF₃) ₃-2,4,6]₂P}^-

Matthew G. Davidson, Keith B. Dillon, Judith A.K. Howard, Sarah Lamb, Mark D. Roden

Durham University

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

Abstract

The synthesis of a bulky secondary phosphine, Ar₂PH [Ar = C₆H₂(CF₃)₃-2,4,6], and its use in the first synthesis and isolation of a phosphonium phosphide, (Ph₃PMe) + (Ar₂P)^-, via the deprotonation of Ar₂PH with a nonstabilised phosphorus ylide, Ph₃P=CH₂, are reported. An X-ray structure of this salt reveals that cations and anions are weakly associated in the solid state through C-H ⋯ P interactions.

Original language	English
Pages (from-to)	481-484
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	550
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(97)00561-5
Publication status	Published - 15 Jan 1998

Keywords

Phosphide
Phosphonium
X-ray diffraction
Ylide

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(97)00561-5

Cite this

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title = "The first synthesis, isolation and X-ray structure of a phosphonium phosphide, (Ph3PMe)+\{[C6H2(CF3) 3-2,4,6]2P\}-",

abstract = "The synthesis of a bulky secondary phosphine, Ar2PH [Ar = C6H2(CF3)3-2,4,6], and its use in the first synthesis and isolation of a phosphonium phosphide, (Ph3PMe) + (Ar2P)-, via the deprotonation of Ar2PH with a nonstabilised phosphorus ylide, Ph3P=CH2, are reported. An X-ray structure of this salt reveals that cations and anions are weakly associated in the solid state through C-H ⋯ P interactions.",

keywords = "Phosphide, Phosphonium, X-ray diffraction, Ylide",

author = "Davidson, \{Matthew G.\} and Dillon, \{Keith B.\} and Howard, \{Judith A.K.\} and Sarah Lamb and Roden, \{Mark D.\}",

year = "1998",

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doi = "10.1016/S0022-328X(97)00561-5",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - The first synthesis, isolation and X-ray structure of a phosphonium phosphide, (Ph3PMe)+{[C6H2(CF3) 3-2,4,6]2P}-

AU - Davidson, Matthew G.

AU - Dillon, Keith B.

AU - Howard, Judith A.K.

AU - Lamb, Sarah

AU - Roden, Mark D.

PY - 1998/1/15

Y1 - 1998/1/15

N2 - The synthesis of a bulky secondary phosphine, Ar2PH [Ar = C6H2(CF3)3-2,4,6], and its use in the first synthesis and isolation of a phosphonium phosphide, (Ph3PMe) + (Ar2P)-, via the deprotonation of Ar2PH with a nonstabilised phosphorus ylide, Ph3P=CH2, are reported. An X-ray structure of this salt reveals that cations and anions are weakly associated in the solid state through C-H ⋯ P interactions.

AB - The synthesis of a bulky secondary phosphine, Ar2PH [Ar = C6H2(CF3)3-2,4,6], and its use in the first synthesis and isolation of a phosphonium phosphide, (Ph3PMe) + (Ar2P)-, via the deprotonation of Ar2PH with a nonstabilised phosphorus ylide, Ph3P=CH2, are reported. An X-ray structure of this salt reveals that cations and anions are weakly associated in the solid state through C-H ⋯ P interactions.

KW - Phosphide

KW - Phosphonium

KW - X-ray diffraction

KW - Ylide

UR - https://www.scopus.com/pages/publications/0000038093

U2 - 10.1016/S0022-328X(97)00561-5

DO - 10.1016/S0022-328X(97)00561-5

M3 - Article

AN - SCOPUS:0000038093

SN - 0022-328X

VL - 550

SP - 481

EP - 484

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -