TY - JOUR
T1 - The first structurally characterised sodium primary amide complex; synthesis and crystal structure of 2-PhOC6H4NHNa·NMe[(CH2) 2NMe2]2
AU - Cragg-Hine, Ian
AU - Davidson, Matthew G.
AU - Edwards, Andrew J.
AU - Raithby, Paul R.
AU - Snaith, Ronald
PY - 1994
Y1 - 1994
N2 - The compound 2-PhOC6H4NHNa·NMe[(CH2) 2NMe2]2has been synthesised by a 1:1 reaction of sodium hydride with 2-phenoxyaniline in toluene in the presence of N,N,N′,N″,N″-pentamethyldiethylene-triamine (pmdien); X-ray crystallography revealed a solid-state structure comprising a near-symmetrical Na2N2 ring dimer with each sodium cation chelated by a tridentate pmdien ligand in an unprecedented near-planar conformation.
AB - The compound 2-PhOC6H4NHNa·NMe[(CH2) 2NMe2]2has been synthesised by a 1:1 reaction of sodium hydride with 2-phenoxyaniline in toluene in the presence of N,N,N′,N″,N″-pentamethyldiethylene-triamine (pmdien); X-ray crystallography revealed a solid-state structure comprising a near-symmetrical Na2N2 ring dimer with each sodium cation chelated by a tridentate pmdien ligand in an unprecedented near-planar conformation.
UR - http://www.scopus.com/inward/record.url?scp=37049078351&partnerID=8YFLogxK
U2 - 10.1039/DT9940002901
DO - 10.1039/DT9940002901
M3 - Article
AN - SCOPUS:37049078351
SN - 1472-7773
SP - 2901
EP - 2902
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 19
ER -