TY - JOUR
T1 - The first structurally characterised example of a manganese(II) complex with monodentate thione ligands; the crystal and molecular structure of trans-dichloro{tetrakis(2(1H)-pyridinethione-S)}manganese(II)
AU - Constable, Edwin C.
AU - King, Adam C.
AU - Palmer, Catherine A.
AU - Raithby, Paul R.
PY - 1991/6/1
Y1 - 1991/6/1
N2 - The reaction of 2(1H)-pyridinethione (HL) with manganese(II) chloride in ethanolic solution results in the formation of the yellow octahedral complex [Mn(HL)4Cl2]; the crystal and molecular structure of the complex reveals that the two chloride ligands occupy trans axial sites and the four thione ligands are S bonded in the equatorial positions (crystallographic data: space group C2/c, a=13.038(1), b=11.184(1), c=17.353(1) Å, β=104.61(1)°, Z=4, 1940 reflections with F≥4σ(F), R=0.029).
AB - The reaction of 2(1H)-pyridinethione (HL) with manganese(II) chloride in ethanolic solution results in the formation of the yellow octahedral complex [Mn(HL)4Cl2]; the crystal and molecular structure of the complex reveals that the two chloride ligands occupy trans axial sites and the four thione ligands are S bonded in the equatorial positions (crystallographic data: space group C2/c, a=13.038(1), b=11.184(1), c=17.353(1) Å, β=104.61(1)°, Z=4, 1940 reflections with F≥4σ(F), R=0.029).
UR - http://www.scopus.com/inward/record.url?scp=0002074670&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)83043-1
DO - 10.1016/S0020-1693(00)83043-1
M3 - Article
AN - SCOPUS:0002074670
SN - 0020-1693
VL - 184
SP - 43
EP - 45
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -