The first structural characterization of a sulfoximidium salt

John J. Longridge; Jeremy M. Rawson; Neil Feeder; Paul R. Raithby

doi:10.1107/S0108270197016569

The first structural characterization of a sulfoximidium salt

John J. Longridge, Jeremy M. Rawson, Neil Feeder, Paul R. Raithby

University of Cambridge

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Abstract

The title compound, diphenylsulfoximidium hydrogen sulfate, C₁₂H₁₂NOS⁺.HSO₄^-, was formed as a hydrolysis product during recrystallization of the product of the reaction of Ph₂SO with (NSCl)₃. Hydrogen-bonded networks link the cation and anion, the latter forming a hydrogen-bonded dimer.

Original language	English
Pages (from-to)	398-399
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	3
DOIs	https://doi.org/10.1107/S0108270197016569
Publication status	Published - 15 Mar 1998

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "The first structural characterization of a sulfoximidium salt",

abstract = "The title compound, diphenylsulfoximidium hydrogen sulfate, C12H12NOS+.HSO4-, was formed as a hydrolysis product during recrystallization of the product of the reaction of Ph2SO with (NSCl)3. Hydrogen-bonded networks link the cation and anion, the latter forming a hydrogen-bonded dimer.",

author = "Longridge, {John J.} and Rawson, {Jeremy M.} and Neil Feeder and Raithby, {Paul R.}",

year = "1998",

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language = "English",

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publisher = "International Union of Crystallography",

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AU - Longridge, John J.

AU - Rawson, Jeremy M.

AU - Feeder, Neil

AU - Raithby, Paul R.

PY - 1998/3/15

Y1 - 1998/3/15

N2 - The title compound, diphenylsulfoximidium hydrogen sulfate, C12H12NOS+.HSO4-, was formed as a hydrolysis product during recrystallization of the product of the reaction of Ph2SO with (NSCl)3. Hydrogen-bonded networks link the cation and anion, the latter forming a hydrogen-bonded dimer.

AB - The title compound, diphenylsulfoximidium hydrogen sulfate, C12H12NOS+.HSO4-, was formed as a hydrolysis product during recrystallization of the product of the reaction of Ph2SO with (NSCl)3. Hydrogen-bonded networks link the cation and anion, the latter forming a hydrogen-bonded dimer.

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U2 - 10.1107/S0108270197016569

DO - 10.1107/S0108270197016569

M3 - Article

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SN - 0108-2701

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EP - 399

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 3

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The first structural characterization of a sulfoximidium salt

Abstract

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