The first stable lithium complex of a pentadentate macrocycle incorporating sp2-nitrogen donor atoms only; the x-ray crystal structure of [Li(L2)(MeOH)][PF6] {L2 = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}

Edwin C. Constable; Lap Yan Chung; Jack Lewis; Paul R. Raithby

doi:10.1039/C39860001719

The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}

Edwin C. Constable, Lap Yan Chung, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The preparation and structural characterisation of a lithium complex of a pentadentate macrocycle incorporating only pyridine and imine donors is described; the metal is in a very unusual pentagonal-based pyramidal environment, in which the sixth axial site is occupied by a solvent methanol molecule.

Original language	English
Pages (from-to)	1719-1720
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39860001719
Publication status	Published - 31 Dec 1986

ASJC Scopus subject areas

Molecular Medicine

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Constable, E. C., Chung, L. Y., Lewis, J., & Raithby, P. R. (1986). The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}. Journal of the Chemical Society, Chemical Communications, (23), 1719-1720. https://doi.org/10.1039/C39860001719

The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}. / Constable, Edwin C.; Chung, Lap Yan; Lewis, Jack et al.
In: Journal of the Chemical Society, Chemical Communications, No. 23, 31.12.1986, p. 1719-1720.

Research output: Contribution to journal › Article › peer-review

Constable, EC, Chung, LY, Lewis, J & Raithby, PR 1986, 'The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}', Journal of the Chemical Society, Chemical Communications, no. 23, pp. 1719-1720. https://doi.org/10.1039/C39860001719

Constable EC, Chung LY, Lewis J, Raithby PR. The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}. Journal of the Chemical Society, Chemical Communications. 1986 Dec 31;(23):1719-1720. doi: 10.1039/C39860001719

Constable, Edwin C. ; Chung, Lap Yan ; Lewis, Jack et al. / The first stable lithium complex of a pentadentate macrocycle incorporating sp²-nitrogen donor atoms only; the x-ray crystal structure of [Li(L²)(MeOH)][PF₆] {L² = 6,13-(bis-2- hydroxyethyl)-6H,13H-tripyrido[cd,fg,lm] [1,2,4,7,9,10,13]heptaazapentadecine}. In: Journal of the Chemical Society, Chemical Communications. 1986 ; No. 23. pp. 1719-1720.

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