The First Solid-State Structure of a Lithiated Diazomethane with C-Li and N-Li Bonds: {[Me3SiC(Li)N2]2·3 THF}∞

Neil Feeder; Mark A. Hendy; Paul R. Raithby; Ronald Snaith; Andrew E.H. Wheatley

doi:10.1002/(sici)1099-0690(199805)1998:5<861::aid-ejoc861>3.0.co;2-j

The First Solid-State Structure of a Lithiated Diazomethane with C-Li and N-Li Bonds: {[Me₃SiC(Li)N₂]₂·3 THF}_∞

Neil Feeder, Mark A. Hendy, Paul R. Raithby, Ronald Snaith, Andrew E.H. Wheatley

University of Cambridge

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

Reaction of n-butyllithium with Me₃SiCHN₂ in THF affords the first example of a lithiated diazomethane with C-Li and N-Li bonds.

Original language	English
Pages (from-to)	861-864
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	5
DOIs	https://doi.org/10.1002/(sici)1099-0690(199805)1998:5<861::aid-ejoc861>3.0.co;2-j
Publication status	Published - May 1998

Keywords

Diazomethane
Lithiation
Solid-state structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1002/(sici)1099-0690(199805)1998:5<861::aid-ejoc861>3.0.co;2-j

Cite this

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title = "The First Solid-State Structure of a Lithiated Diazomethane with C-Li and N-Li Bonds: {[Me3SiC(Li)N2]2·3 THF}∞",

abstract = "Reaction of n-butyllithium with Me3SiCHN2 in THF affords the first example of a lithiated diazomethane with C-Li and N-Li bonds.",

keywords = "Diazomethane, Lithiation, Solid-state structure",

author = "Neil Feeder and Hendy, {Mark A.} and Raithby, {Paul R.} and Ronald Snaith and Wheatley, {Andrew E.H.}",

year = "1998",

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AU - Feeder, Neil

AU - Hendy, Mark A.

AU - Raithby, Paul R.

AU - Snaith, Ronald

AU - Wheatley, Andrew E.H.

PY - 1998/5

Y1 - 1998/5

N2 - Reaction of n-butyllithium with Me3SiCHN2 in THF affords the first example of a lithiated diazomethane with C-Li and N-Li bonds.

AB - Reaction of n-butyllithium with Me3SiCHN2 in THF affords the first example of a lithiated diazomethane with C-Li and N-Li bonds.

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KW - Lithiation

KW - Solid-state structure

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