TY - JOUR
T1 - The first imino-lead complex
T2 - Synthesis and X-ray characterisation of Pb[μ-N=C(But)Ph]3Li·thf (thf = tetrahydrofuran)
AU - Edwards, Andrew J.
AU - Paver, Michael A.
AU - Raithby, Paul R.
AU - Russell, Christopher A.
AU - Wright, Dominic S.
PY - 1993/1/1
Y1 - 1993/1/1
N2 - The title compound, Pb[N=ButPh]3Li·thf, has been synthesised by nucleophilic substitution of (C5H 5)2 Pb (1 equiv.) with LiN=C(But)(Ph)(2equiv.) and shown by X-ray crystallography to have a distorted trigonal bipyramidal PbN3Li core structure in which the phenyl groups of the imino ligands face towards, and encircle, the Pb.
AB - The title compound, Pb[N=ButPh]3Li·thf, has been synthesised by nucleophilic substitution of (C5H 5)2 Pb (1 equiv.) with LiN=C(But)(Ph)(2equiv.) and shown by X-ray crystallography to have a distorted trigonal bipyramidal PbN3Li core structure in which the phenyl groups of the imino ligands face towards, and encircle, the Pb.
UR - http://www.scopus.com/inward/record.url?scp=37049078785&partnerID=8YFLogxK
U2 - 10.1039/C39930001086
DO - 10.1039/C39930001086
M3 - Article
AN - SCOPUS:37049078785
SN - 0022-4936
SP - 1086
EP - 1088
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 13
ER -