The first crystallographically-characterised Cu(II) xanthate

A.L. Johnson; M.S. Hill; Gabriele Kociok-Kohn; K.C. Molloy; A.L. Sudlow

doi:10.1016/j.inoche.2014.09.003

The first crystallographically-characterised Cu(II) xanthate

A.L. Johnson, M.S. Hill, Gabriele Kociok-Kohn, K.C. Molloy, A.L. Sudlow

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Abstract

The copper(II) xanthate Cu(S₂COEt)₂·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu₂S.

Original language	English
Pages (from-to)	8-11
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	49
Early online date	3 Sept 2014
DOIs	https://doi.org/10.1016/j.inoche.2014.09.003
Publication status	Published - Nov 2014

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10.1016/j.inoche.2014.09.003

first_crystallFinal published version, 399 KBLicence: CC BY-NC-ND

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title = "The first crystallographically-characterised Cu(II) xanthate",

abstract = "The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.",

author = "A.L. Johnson and M.S. Hill and Gabriele Kociok-Kohn and K.C. Molloy and A.L. Sudlow",

year = "2014",

month = nov,

doi = "10.1016/j.inoche.2014.09.003",

language = "English",

volume = "49",

pages = "8--11",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - The first crystallographically-characterised Cu(II) xanthate

AU - Johnson, A.L.

AU - Hill, M.S.

AU - Kociok-Kohn, Gabriele

AU - Molloy, K.C.

AU - Sudlow, A.L.

PY - 2014/11

Y1 - 2014/11

N2 - The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.

AB - The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.

UR - http://www.scopus.com/inward/record.url?scp=84907463887&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1016/j.inoche.2014.09.003

U2 - 10.1016/j.inoche.2014.09.003

DO - 10.1016/j.inoche.2014.09.003

M3 - Article

AN - SCOPUS:84907463887

SN - 1387-7003

VL - 49

SP - 8

EP - 11

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

The first crystallographically-characterised Cu(II) xanthate

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Scalable, Low-Cost Organic Photovoltaic Devices

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The first crystallographically-characterised Cu(II) xanthate

Abstract

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Scalable, Low-Cost Organic Photovoltaic Devices

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MC2-Electron Microscopy (EM)

MC2- X-ray diffraction (XRD)

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