Projects per year
Abstract
The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.
Original language | English |
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Pages (from-to) | 8-11 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 49 |
Early online date | 3 Sept 2014 |
DOIs | |
Publication status | Published - Nov 2014 |
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Dive into the research topics of 'The first crystallographically-characterised Cu(II) xanthate'. Together they form a unique fingerprint.Projects
- 1 Finished
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Scalable, Low-Cost Organic Photovoltaic Devices
Hill, M. (PI), Johnson, A. (CoI) & Molloy, K. C. (CoI)
Engineering and Physical Sciences Research Council
13/06/11 → 12/06/14
Project: Research council
Equipment
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MC2-Electron Microscopy (EM)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type
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MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)Facility/equipment: Technology type