The first crystallographically-characterised Cu(II) xanthate

A.L. Johnson, M.S. Hill, Gabriele Kociok-Kohn, K.C. Molloy, A.L. Sudlow

Research output: Contribution to journalArticle

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Abstract

The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.

LanguageEnglish
Pages8-11
Number of pages4
JournalInorganic Chemistry Communications
Volume49
Early online date3 Sep 2014
DOIs
StatusPublished - Nov 2014

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Copper
copper
chelation
Film growth
Chelation
Aerosols
thermal decomposition
Chemical vapor deposition
aerosols
Pyrolysis
Metals
Ligands
vapor deposition
Oxidation
ligands
oxidation
metals
phenyllithium
N,N,N',N'-tetramethylethylenediamine

Cite this

The first crystallographically-characterised Cu(II) xanthate. / Johnson, A.L.; Hill, M.S.; Kociok-Kohn, Gabriele; Molloy, K.C.; Sudlow, A.L.

In: Inorganic Chemistry Communications, Vol. 49, 11.2014, p. 8-11.

Research output: Contribution to journalArticle

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AU - Sudlow, A.L.

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