The electrochemical reduction of an unsaturated mixed-metal cluster anion: Synthesis and x-ray crystal structure of [(Ph3P)2N][{Os3H(CO)10}2Ag]

Mariano Fajardo; M. Pilar Gómez-Sal; H. Diane Holden; Brian F.G. Johnson; Jack Lewis; Roderick C.S. McQueen; Paul R. Raithby

doi:10.1016/0022-328X(84)80205-3

The electrochemical reduction of an unsaturated mixed-metal cluster anion: Synthesis and x-ray crystal structure of [(Ph₃P)₂N][{Os₃H(CO)₁₀}₂Ag]

Mariano Fajardo, M. Pilar Gómez-Sal, H. Diane Holden, Brian F.G. Johnson, Jack Lewis, Roderick C.S. McQueen, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The unsaturated mixed-metal cluster anion [{Os₃H(CO)₁₀}₂Ag]^- has been prepared by the reaction of [(Ph₃P)₂N][Os₃H(CO)₁₁] with Ag[PF₆], and the anion has been shown by an X-ray analysis to consist of an Ag^I atom linking together two "Os₃H(CO)₁₀" fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions.

Original language	English
Pages (from-to)	c25-c28
Journal	Journal of Organometallic Chemistry
Volume	267
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(84)80205-3
Publication status	Published - 5 Jun 1984

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(84)80205-3

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@article{662808948bf1487d8baacd2f01d97465,

title = "The electrochemical reduction of an unsaturated mixed-metal cluster anion: Synthesis and x-ray crystal structure of [(Ph3P)2N][\{Os3H(CO)10\}2Ag]",

abstract = "The unsaturated mixed-metal cluster anion [\{Os3H(CO)10\}2Ag]- has been prepared by the reaction of [(Ph3P)2N][Os3H(CO)11] with Ag[PF6], and the anion has been shown by an X-ray analysis to consist of an AgI atom linking together two {"}Os3H(CO)10{"} fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions.",

author = "Mariano Fajardo and \{Pilar G{\'o}mez-Sal\}, M. and Holden, \{H. Diane\} and Johnson, \{Brian F.G.\} and Jack Lewis and McQueen, \{Roderick C.S.\} and Raithby, \{Paul R.\}",

year = "1984",

month = jun,

day = "5",

doi = "10.1016/0022-328X(84)80205-3",

language = "English",

volume = "267",

pages = "c25--c28",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - The electrochemical reduction of an unsaturated mixed-metal cluster anion

T2 - Synthesis and x-ray crystal structure of [(Ph3P)2N][{Os3H(CO)10}2Ag]

AU - Fajardo, Mariano

AU - Pilar Gómez-Sal, M.

AU - Holden, H. Diane

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - McQueen, Roderick C.S.

AU - Raithby, Paul R.

PY - 1984/6/5

Y1 - 1984/6/5

N2 - The unsaturated mixed-metal cluster anion [{Os3H(CO)10}2Ag]- has been prepared by the reaction of [(Ph3P)2N][Os3H(CO)11] with Ag[PF6], and the anion has been shown by an X-ray analysis to consist of an AgI atom linking together two "Os3H(CO)10" fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions.

AB - The unsaturated mixed-metal cluster anion [{Os3H(CO)10}2Ag]- has been prepared by the reaction of [(Ph3P)2N][Os3H(CO)11] with Ag[PF6], and the anion has been shown by an X-ray analysis to consist of an AgI atom linking together two "Os3H(CO)10" fragments. The electrochemistry of this complex has been investigated and it has been shown to undergo two one-electron reductions.

UR - https://www.scopus.com/pages/publications/0042916848

U2 - 10.1016/0022-328X(84)80205-3

DO - 10.1016/0022-328X(84)80205-3

M3 - Article

AN - SCOPUS:0042916848

SN - 0022-328X

VL - 267

SP - c25-c28

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

The electrochemical reduction of an unsaturated mixed-metal cluster anion: Synthesis and x-ray crystal structure of [(Ph₃P)₂N][{Os₃H(CO)₁₀}₂Ag]

Abstract

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