The Direct Synthesis of H                         
                        2
                                                 O                         
                        2
                                                  Using TS-1 Supported Catalysts

Richard J. Lewis; Kenji Ueura; Yukimasa Fukuta; Simon J. Freakley; Liqun Kang; Ryan Wang; Qian He; Jennifer K. Edwards; David J. Morgan; Yasushi Yamamoto; Graham J. Hutchings

doi:10.1002/cctc.201900100

The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts

Richard J. Lewis, Kenji Ueura, Yukimasa Fukuta, Simon J. Freakley, Liqun Kang, Ryan Wang, Qian He, Jennifer K. Edwards, David J. Morgan, Yasushi Yamamoto, Graham J. Hutchings

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (SciVal)

48 Downloads (Pure)

Abstract

In this study we show that using AuPd nanoparticles supported on a commercial titanium silicate (TS-1) prepared using a wet co-impregnation method it is possible to produce hydrogen peroxide from molecular H ₂ and O ₂ via the direct synthesis reaction. The effect of Au: Pd ratio and calcination temperature is evaluated as well as the role of Pt addition to the AuPd supported catalysts. The effect of Pt addition to AuPt nanoparticles is observed to result in a significant improvement in catalytic activity and selectivity to hydrogen peroxide with detailed characterisation indicating this is a result of selectively tuning the ratio of Pd oxidation states.

Original language	English
Pages (from-to)	1673-1680
Journal	ChemCatChem
Volume	11
Issue number	6
Early online date	5 Mar 2019
DOIs	https://doi.org/10.1002/cctc.201900100
Publication status	Published - 20 Mar 2019

Keywords

Au−Pd-Pt
Green Chemistry
Hydrogen Peroxide
TS-1

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1002/cctc.201900100

The_Direct_Synthesis_of_H2O2_Using_TS_1_Supported_Catalysts (3)
This is the peer reviewed version of the following article: Lewis, R. J et al. The direct synthesis of H2O2 using TS-1 supported catalysts. ChemCatChem. 2019, 11, pp. 1673-1680, which has been published in final form at https://onlinelibrary.wiley.com/doi/full/10.1002/cctc.201900100. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 590 KB

Cite this

Lewis, R. J., Ueura, K., Fukuta, Y., Freakley, S. J., Kang, L., Wang, R., He, Q., Edwards, J. K., Morgan, D. J., Yamamoto, Y., & Hutchings, G. J. (2019). The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts. ChemCatChem, 11(6), 1673-1680. https://doi.org/10.1002/cctc.201900100

The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts. / Lewis, Richard J.; Ueura, Kenji; Fukuta, Yukimasa et al.
In: ChemCatChem, Vol. 11, No. 6, 20.03.2019, p. 1673-1680.

Research output: Contribution to journal › Article › peer-review

Lewis, RJ, Ueura, K, Fukuta, Y, Freakley, SJ, Kang, L, Wang, R, He, Q, Edwards, JK, Morgan, DJ, Yamamoto, Y & Hutchings, GJ 2019, 'The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts', ChemCatChem, vol. 11, no. 6, pp. 1673-1680. https://doi.org/10.1002/cctc.201900100

Lewis RJ, Ueura K, Fukuta Y, Freakley SJ, Kang L, Wang R et al. The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts. ChemCatChem. 2019 Mar 20;11(6):1673-1680. Epub 2019 Mar 5. doi: 10.1002/cctc.201900100

Lewis, Richard J. ; Ueura, Kenji ; Fukuta, Yukimasa et al. / The Direct Synthesis of H ₂ O ₂ Using TS-1 Supported Catalysts. In: ChemCatChem. 2019 ; Vol. 11, No. 6. pp. 1673-1680.

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