The Determination of Thermodynamic Properties of Polymer Solutions by Finite-Concentration Gas Chromatography

G. J. Price; J. E. Guillet

doi:10.1080/00222338608081138

The Determination of Thermodynamic Properties of Polymer Solutions by Finite-Concentration Gas Chromatography

G. J. Price, J. E. Guillet

Department of Chemistry

Research output: Contribution to journal › Article

Abstract

Although the technique of gas chromatography has been widely used to study polymer properties and to obtain information on polymer solution thermodynamics, few workers have extended their results beyond infinite dilution of solvent, Finite-concentration gas chromatography has been used to study several poly (dimethylsi1oxane)- solvent systems at 25ºC. The results are in good agreement with those obtained by traditional vapor sorption methods. A comparison of the various available techniques has been made, and the advantages and disadvantages of each are discussed.

Original language	English
Pages (from-to)	1487-1502
Number of pages	16
Journal	Journal of Macromolecular Science: Part A - Chemistry
Volume	23
Issue number	12
DOIs	https://doi.org/10.1080/00222338608081138
Publication status	Published - 1 Jan 1986

ASJC Scopus subject areas

Engineering(all)

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10.1080/00222338608081138

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Cite this

Price, G. J., & Guillet, J. E. (1986). The Determination of Thermodynamic Properties of Polymer Solutions by Finite-Concentration Gas Chromatography. Journal of Macromolecular Science: Part A - Chemistry, 23(12), 1487-1502. https://doi.org/10.1080/00222338608081138

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