Abstract
Although the technique of gas chromatography has been widely used to study polymer properties and to obtain information on polymer solution thermodynamics, few workers have extended their results beyond infinite dilution of solvent, Finite-concentration gas chromatography has been used to study several poly (dimethylsi1oxane)- solvent systems at 25ºC. The results are in good agreement with those obtained by traditional vapor sorption methods. A comparison of the various available techniques has been made, and the advantages and disadvantages of each are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 1487-1502 |
| Number of pages | 16 |
| Journal | Journal of Macromolecular Science: Part A - Chemistry |
| Volume | 23 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 1 Jan 1986 |
ASJC Scopus subject areas
- Engineering(all)
Cite this
The Determination of Thermodynamic Properties of Polymer Solutions by Finite-Concentration Gas Chromatography. / Price, G. J.; Guillet, J. E.
In: Journal of Macromolecular Science: Part A - Chemistry, Vol. 23, No. 12, 01.01.1986, p. 1487-1502.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The Determination of Thermodynamic Properties of Polymer Solutions by Finite-Concentration Gas Chromatography
AU - Price, G. J.
AU - Guillet, J. E.
PY - 1986/1/1
Y1 - 1986/1/1
N2 - Although the technique of gas chromatography has been widely used to study polymer properties and to obtain information on polymer solution thermodynamics, few workers have extended their results beyond infinite dilution of solvent, Finite-concentration gas chromatography has been used to study several poly (dimethylsi1oxane)- solvent systems at 25ºC. The results are in good agreement with those obtained by traditional vapor sorption methods. A comparison of the various available techniques has been made, and the advantages and disadvantages of each are discussed.
AB - Although the technique of gas chromatography has been widely used to study polymer properties and to obtain information on polymer solution thermodynamics, few workers have extended their results beyond infinite dilution of solvent, Finite-concentration gas chromatography has been used to study several poly (dimethylsi1oxane)- solvent systems at 25ºC. The results are in good agreement with those obtained by traditional vapor sorption methods. A comparison of the various available techniques has been made, and the advantages and disadvantages of each are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0022863813&partnerID=8YFLogxK
U2 - 10.1080/00222338608081138
DO - 10.1080/00222338608081138
M3 - Article
VL - 23
SP - 1487
EP - 1502
JO - Journal of Macromolecular Science: Part A - Chemistry
JF - Journal of Macromolecular Science: Part A - Chemistry
SN - 0022-233X
IS - 12
ER -