The coordination of Cu(II) in a concentrated copper nitrate solution

P. S. Salmon; G. W. Neilson

doi:10.1088/0953-8984/1/31/028

The coordination of Cu(II) in a concentrated copper nitrate solution

P. S. Salmon, G. W. Neilson

Institut Laue Langevin

Research output: Contribution to journal › Article › peer-review

Abstract

The first-order difference method of neutron diffraction has been applied to a 1.00 molal (mol kg^-1) Cu(NO₃)₂ heavy water solution. The results show a nearest-neighbour distance given by r _CuO=1.96+or-0.03 AA, a hydration number n⁰ _Cu=4.0+or-0.2 and are consistent with a Jahn-Teller distortion of the Cu²⁺(aq) complex to give a (4+2) coordination group.

Original language	English
Article number	028
Pages (from-to)	5291-5295
Number of pages	5
Journal	Journal of Physics: Condensed Matter
Volume	1
Issue number	31
DOIs	https://doi.org/10.1088/0953-8984/1/31/028
Publication status	Published - 1 Dec 1989

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics

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abstract = "The first-order difference method of neutron diffraction has been applied to a 1.00 molal (mol kg-1) Cu(NO3)2 heavy water solution. The results show a nearest-neighbour distance given by r CuO=1.96+or-0.03 AA, a hydration number n0 Cu=4.0+or-0.2 and are consistent with a Jahn-Teller distortion of the Cu2+(aq) complex to give a (4+2) coordination group.",

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AB - The first-order difference method of neutron diffraction has been applied to a 1.00 molal (mol kg-1) Cu(NO3)2 heavy water solution. The results show a nearest-neighbour distance given by r CuO=1.96+or-0.03 AA, a hydration number n0 Cu=4.0+or-0.2 and are consistent with a Jahn-Teller distortion of the Cu2+(aq) complex to give a (4+2) coordination group.

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The coordination of Cu(II) in a concentrated copper nitrate solution

Abstract

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