The B-N bond controls the balance between locally excited (LE) and twisted internal charge transfer (TICT) states observed for aniline based fluorescent saccharide sensors

L I Bosch; M F Mahon; T D James

doi:10.1016/j.tetlet.2004.01.112

The B-N bond controls the balance between locally excited (LE) and twisted internal charge transfer (TICT) states observed for aniline based fluorescent saccharide sensors

L I Bosch, M F Mahon, T D James

Department of Chemistry

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48 Citations (SciVal)

Abstract

Three boronic acid based saccharide sensors with an aniline fluorophore have been prepared. One of the systems (1a) contains an intramolecular boron-nitrogen (B-N) bond and displays fluorescence due to both LE and TICT states. The other two systems (1b and c) have no B-N bond and only Show fluorescence due to the LE state. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2859-2862
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	13
DOIs	https://doi.org/10.1016/j.tetlet.2004.01.112
Publication status	Published - 2004

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ID number: ISI:000220324300035

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10.1016/j.tetlet.2004.01.112

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title = "The B-N bond controls the balance between locally excited (LE) and twisted internal charge transfer (TICT) states observed for aniline based fluorescent saccharide sensors",

abstract = "Three boronic acid based saccharide sensors with an aniline fluorophore have been prepared. One of the systems (1a) contains an intramolecular boron-nitrogen (B-N) bond and displays fluorescence due to both LE and TICT states. The other two systems (1b and c) have no B-N bond and only Show fluorescence due to the LE state. (C) 2004 Elsevier Ltd. All rights reserved.",

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AU - Mahon, M F

AU - James, T D

N1 - ID number: ISI:000220324300035

PY - 2004

Y1 - 2004

N2 - Three boronic acid based saccharide sensors with an aniline fluorophore have been prepared. One of the systems (1a) contains an intramolecular boron-nitrogen (B-N) bond and displays fluorescence due to both LE and TICT states. The other two systems (1b and c) have no B-N bond and only Show fluorescence due to the LE state. (C) 2004 Elsevier Ltd. All rights reserved.

AB - Three boronic acid based saccharide sensors with an aniline fluorophore have been prepared. One of the systems (1a) contains an intramolecular boron-nitrogen (B-N) bond and displays fluorescence due to both LE and TICT states. The other two systems (1b and c) have no B-N bond and only Show fluorescence due to the LE state. (C) 2004 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tetlet.2004.01.112

DO - 10.1016/j.tetlet.2004.01.112

M3 - Article

SN - 0040-4039

VL - 45

SP - 2859

EP - 2862

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 13

ER -

The B-N bond controls the balance between locally excited (LE) and twisted internal charge transfer (TICT) states observed for aniline based fluorescent saccharide sensors

Abstract

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