The application of ultrasound to the synthesis of poly(organosilanes)

G. J. Price; A. M. Patel

doi:10.1016/S0014-3057(96)00084-5

The application of ultrasound to the synthesis of poly(organosilanes)

G. J. Price, A. M. Patel

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (SciVal)

Abstract

The effect of carrying out Wurtz type polymerizations of dichlorodiorganosilanes to poly(organosilanes) under the influence of ultrasound has been investigated. The sonochemical reaction produced faster polymerizations and higher yields in a range of systems. Previous reports of modification of molecular weight distributions have been confirmed and the results used to elucidate the mechanism of the sonochemical enhancement. The control of molecular weight distributions by variation of the ultrasound properties is also illustrated.

Original language	English
Pages (from-to)	1289-1295
Number of pages	7
Journal	European Polymer Journal
Volume	32
Issue number	11
DOIs	https://doi.org/10.1016/S0014-3057(96)00084-5
Publication status	Published - Nov 1996

ASJC Scopus subject areas

General Physics and Astronomy
Polymers and Plastics
Organic Chemistry

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10.1016/S0014-3057(96)00084-5

Cite this

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abstract = "The effect of carrying out Wurtz type polymerizations of dichlorodiorganosilanes to poly(organosilanes) under the influence of ultrasound has been investigated. The sonochemical reaction produced faster polymerizations and higher yields in a range of systems. Previous reports of modification of molecular weight distributions have been confirmed and the results used to elucidate the mechanism of the sonochemical enhancement. The control of molecular weight distributions by variation of the ultrasound properties is also illustrated.",

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AB - The effect of carrying out Wurtz type polymerizations of dichlorodiorganosilanes to poly(organosilanes) under the influence of ultrasound has been investigated. The sonochemical reaction produced faster polymerizations and higher yields in a range of systems. Previous reports of modification of molecular weight distributions have been confirmed and the results used to elucidate the mechanism of the sonochemical enhancement. The control of molecular weight distributions by variation of the ultrasound properties is also illustrated.

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The application of ultrasound to the synthesis of poly(organosilanes)

Abstract

ASJC Scopus subject areas

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