Tetraphenylpentalenide organolanthanide complexes

Nicholas J. Katzer; Mandeep Kaur; Asmita Sen; Rupal Nimaiyar; Jochen Autschbach; Polly L. Arnold; Ulrich Hintermair

doi:10.1039/d4cc02570a

Tetraphenylpentalenide organolanthanide complexes

Nicholas J. Katzer, Mandeep Kaur, Asmita Sen, Rupal Nimaiyar, Jochen Autschbach, Polly L. Arnold, Ulrich Hintermair

Research output: Contribution to journal › Article › peer-review

Abstract

The D_2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) Ln^III sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

Original language	English
Pages (from-to)	9749-9752
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	72
Early online date	12 Jul 2024
DOIs	https://doi.org/10.1039/d4cc02570a
Publication status	Published - 16 Sept 2024

Data Availability Statement

Crystallographic datasets are available from the CCDC deposition numbers 2332849, 2357823–2357832 and other analytical data can be retrieved via DOI: https://doi.org/10.5061/dryad.sxksn03bf.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d4cc02570aLicence: CC BY

Cite this

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abstract = "The D2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) LnIII sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.",

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T1 - Tetraphenylpentalenide organolanthanide complexes

AU - Katzer, Nicholas J.

AU - Kaur, Mandeep

AU - Sen, Asmita

AU - Nimaiyar, Rupal

AU - Autschbach, Jochen

AU - Arnold, Polly L.

AU - Hintermair, Ulrich

PY - 2024/9/16

Y1 - 2024/9/16

N2 - The D2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) LnIII sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

AB - The D2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) LnIII sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

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U2 - 10.1039/d4cc02570a

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M3 - Article

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ER -

Tetraphenylpentalenide organolanthanide complexes

Abstract

Data Availability Statement

ASJC Scopus subject areas

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