TY - JOUR
T1 - Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate
AU - Sow, Y.
AU - Diop, L.
AU - Molloy, K.C.
AU - Kociok-Kohn, Gabriele
PY - 2013/2
Y1 - 2013/2
N2 - The SnIV atom in the title compound, [(CH3)4N] [Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N] 2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the SnIV atom is distorted octahedral. The anions are connected by the lattice water molecule through O - H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C - H⋯O and C - H⋯Cl interactions.
AB - The SnIV atom in the title compound, [(CH3)4N] [Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N] 2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the SnIV atom is distorted octahedral. The anions are connected by the lattice water molecule through O - H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C - H⋯O and C - H⋯Cl interactions.
UR - http://www.scopus.com/inward/record.url?scp=84873403703&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1107/S1600536813000895
U2 - 10.1107/S1600536813000895
DO - 10.1107/S1600536813000895
M3 - Article
AN - SCOPUS:84873403703
SN - 1600-5368
VL - 69
SP - m106-m107
JO - Acta Crystallographica Section E-Structure Reports Online
JF - Acta Crystallographica Section E-Structure Reports Online
IS - 2
ER -