Tetraazaoctaphyrin - A biimidazole-containing expanded porphyrin

Jonathan L. Sessler; Bobbi L. Rubin; Marcin Stepien; Thomas Koehler; G. Dan Pantos; Vladimir Roznyatovskiy

doi:10.1139/V06-068

Tetraazaoctaphyrin - A biimidazole-containing expanded porphyrin

Jonathan L. Sessler, Bobbi L. Rubin, Marcin Stepien, Thomas Koehler, G. Dan Pantos, Vladimir Roznyatovskiy

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

A series of expanded porphyrins, incorporating biimidazoles and bipyrroles within their macrocyclic framework, has been synthesized. Insights into the complex conformational characteristics of these systems were obtained from two-dimensional NMR spectroscopic studies. The relative energy values for the various asymmetric structures inferred from these analyses were compared using DFT molecular modeling calculations.

Original language	English
Pages (from-to)	1218-1225
Number of pages	8
Journal	Canadian Journal of Chemistry
Volume	84
Issue number	10
DOIs	https://doi.org/10.1139/V06-068
Publication status	Published - 1 Oct 2006

Keywords

macrocycles
expanded porphyrins
imidazoles
pyrroles
biimidazoles
supramolecular chemistry
heterocycles

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10.1139/V06-068

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abstract = "A series of expanded porphyrins, incorporating biimidazoles and bipyrroles within their macrocyclic framework, has been synthesized. Insights into the complex conformational characteristics of these systems were obtained from two-dimensional NMR spectroscopic studies. The relative energy values for the various asymmetric structures inferred from these analyses were compared using DFT molecular modeling calculations.",

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author = "Sessler, {Jonathan L.} and Rubin, {Bobbi L.} and Marcin Stepien and Thomas Koehler and Pantos, {G. Dan} and Vladimir Roznyatovskiy",

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AU - Sessler, Jonathan L.

AU - Rubin, Bobbi L.

AU - Stepien, Marcin

AU - Koehler, Thomas

AU - Pantos, G. Dan

AU - Roznyatovskiy, Vladimir

PY - 2006/10/1

Y1 - 2006/10/1

N2 - A series of expanded porphyrins, incorporating biimidazoles and bipyrroles within their macrocyclic framework, has been synthesized. Insights into the complex conformational characteristics of these systems were obtained from two-dimensional NMR spectroscopic studies. The relative energy values for the various asymmetric structures inferred from these analyses were compared using DFT molecular modeling calculations.

AB - A series of expanded porphyrins, incorporating biimidazoles and bipyrroles within their macrocyclic framework, has been synthesized. Insights into the complex conformational characteristics of these systems were obtained from two-dimensional NMR spectroscopic studies. The relative energy values for the various asymmetric structures inferred from these analyses were compared using DFT molecular modeling calculations.

KW - macrocycles

KW - expanded porphyrins

KW - imidazoles

KW - pyrroles

KW - biimidazoles

KW - supramolecular chemistry

KW - heterocycles

U2 - 10.1139/V06-068

DO - 10.1139/V06-068

M3 - Article

SN - 0008-4042

VL - 84

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EP - 1225

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 10

ER -

Tetraazaoctaphyrin - A biimidazole-containing expanded porphyrin

Abstract

Keywords

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