Synthetic, Structural and Computational Studies on Heavier Tetragen and Chalcogen Triazenide Complexes

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Abstract

The syntheses of the triazenide complexes [{N(N Dipp) 2} 2M] (Dipp = 2,6-di-isopropylphenyl; M = Ge(II) (1), Sn(II) (2), Pb(II) (3), and Te(II) (5)) are described for the first time. These compounds have been characterized by single-crystal X-ray diffraction and heteronuclear NMR spectroscopy. Density functional theory calculations were employed to confirm the presence and nature of the stereochemically active lone pairs in 1-5, alongside the Gibbs energy changes for their general synthesis, which enable the rationalization of observed reactivities.

Original languageEnglish
Pages (from-to)16660-16666
Number of pages7
JournalInorganic Chemistry
Volume58
Issue number24
Early online date20 Nov 2019
DOIs
Publication statusPublished - 16 Dec 2019

Keywords

  • Triazenide
  • Germanium
  • Tin
  • Lead
  • selenium
  • Tellurium

ASJC Scopus subject areas

  • Chemistry(all)

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