Abstract
The syntheses of the triazenide complexes [{N(N Dipp) 2} 2M] (Dipp = 2,6-di-isopropylphenyl; M = Ge(II) (1), Sn(II) (2), Pb(II) (3), and Te(II) (5)) are described for the first time. These compounds have been characterized by single-crystal X-ray diffraction and heteronuclear NMR spectroscopy. Density functional theory calculations were employed to confirm the presence and nature of the stereochemically active lone pairs in 1-5, alongside the Gibbs energy changes for their general synthesis, which enable the rationalization of observed reactivities.
Original language | English |
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Pages (from-to) | 16660-16666 |
Number of pages | 7 |
Journal | Inorganic Chemistry |
Volume | 58 |
Issue number | 24 |
Early online date | 20 Nov 2019 |
DOIs | |
Publication status | Published - 16 Dec 2019 |
Keywords
- Triazenide
- Germanium
- Tin
- Lead
- selenium
- Tellurium
ASJC Scopus subject areas
- General Chemistry
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Dive into the research topics of 'Synthetic, Structural and Computational Studies on Heavier Tetragen and Chalcogen Triazenide Complexes'. Together they form a unique fingerprint.Profiles
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Andrew Johnson
- Department of Chemistry - Senior Lecturer
- Centre for Sustainable Chemical Technologies (CSCT)
- Centre for Nanoscience and Nanotechnology
- Centre for Doctoral Training in Aerosol Science
- IAAPS: Propulsion and Mobility
- Institute of Sustainability and Climate Change
Person: Research & Teaching, Core staff, Affiliate staff