Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: Novel donor-acceptor heterobimetallic materials

Michael C.B. Colbert; Scott L. Ingham; Jack Lewis; Nicholas J. Long; Paul R. Raithby

doi:10.1039/DT9940002215

Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: Novel donor-acceptor heterobimetallic materials

Michael C.B. Colbert, Scott L. Ingham, Jack Lewis, Nicholas J. Long, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C₅H₅){C₅H ₄C≡C[Os(dppm)₂Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.

Original language	English
Pages (from-to)	2215-2216
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/DT9940002215
Publication status	Published - 1994

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9940002215

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title = "Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: Novel donor-acceptor heterobimetallic materials",

abstract = "Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5)\{C5H 4C≡C[Os(dppm)2Cl]\}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.",

author = "Colbert, \{Michael C.B.\} and Ingham, \{Scott L.\} and Jack Lewis and Long, \{Nicholas J.\} and Raithby, \{Paul R.\}",

year = "1994",

doi = "10.1039/DT9940002215",

language = "English",

pages = "2215--2216",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - Synthetic and structural characterisation of metal complexes of ferrocenylacetylene

T2 - Novel donor-acceptor heterobimetallic materials

AU - Colbert, Michael C.B.

AU - Ingham, Scott L.

AU - Lewis, Jack

AU - Long, Nicholas J.

AU - Raithby, Paul R.

PY - 1994

Y1 - 1994

N2 - Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H 4C≡C[Os(dppm)2Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.

AB - Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H 4C≡C[Os(dppm)2Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.

UR - https://www.scopus.com/pages/publications/37049078259

U2 - 10.1039/DT9940002215

DO - 10.1039/DT9940002215

M3 - Article

AN - SCOPUS:37049078259

SN - 1472-7773

SP - 2215

EP - 2216

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: Novel donor-acceptor heterobimetallic materials

Abstract

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