Synthetic and structural characterisation of metal complexes of ferrocenylacetylene: Novel donor-acceptor heterobimetallic materials

Michael C.B. Colbert, Scott L. Ingham, Jack Lewis, Nicholas J. Long, Paul R. Raithby

Research output: Contribution to journalArticlepeer-review

Abstract

Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H 4C≡C[Os(dppm)2Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.

Original languageEnglish
Pages (from-to)2215-2216
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number14
DOIs
Publication statusPublished - 1994

ASJC Scopus subject areas

  • General Chemistry

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