Synthesis, reactivity, and molecular structure of the raft complex [Os 6(μ3-O)(μ3-CO)(CO)18]

Robert J. Goudsmit; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Kenton H. Whitmire

doi:10.1039/C39830000246

Synthesis, reactivity, and molecular structure of the raft complex [Os ₆(μ₃-O)(μ₃-CO)(CO)₁₈]

Robert J. Goudsmit, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Kenton H. Whitmire

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Os₆(CO)₂₀] reacts with molecular oxygen to give [Os₆(μ₃-O)(μ₃-CO)(CO) ₁₈], which has been shown by an X-ray analysis to contain an Os ₆ raft, the central triangle of which is capped on one side by an O atom and on the other by a carbonyl group; this oxygenated cluster reacts with P(OMe) ₃ to yield the clusters [Os₆(CO) _21-n{P(OMe)₃}_n] (n = 1-6) and the cluster [Os₆(CO)₂₀] also reacts with acetylene to give [Os ₄(CO)₁₂(C₂H₂)] and [Os ₅(CO)₁₃(C₂H₂)₂] and with hydrogen sulphide to give [H₂Os₃(CO)₉S].

Original language	English
Pages (from-to)	246-247
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39830000246
Publication status	Published - 1983

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Molecular Medicine

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@article{0fdedf65e8344c35970b170407a32c66,

title = "Synthesis, reactivity, and molecular structure of the raft complex [Os 6(μ3-O)(μ3-CO)(CO)18]",

abstract = "The cluster [Os6(CO)20] reacts with molecular oxygen to give [Os6(μ3-O)(μ3-CO)(CO) 18], which has been shown by an X-ray analysis to contain an Os 6 raft, the central triangle of which is capped on one side by an O atom and on the other by a carbonyl group; this oxygenated cluster reacts with P(OMe) 3 to yield the clusters [Os6(CO) 21-n\{P(OMe)3\}n] (n = 1-6) and the cluster [Os6(CO)20] also reacts with acetylene to give [Os 4(CO)12(C2H2)] and [Os 5(CO)13(C2H2)2] and with hydrogen sulphide to give [H2Os3(CO)9S].",

author = "Goudsmit, \{Robert J.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Whitmire, \{Kenton H.\}",

year = "1983",

doi = "10.1039/C39830000246",

language = "English",

pages = "246--247",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "5",

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T1 - Synthesis, reactivity, and molecular structure of the raft complex [Os 6(μ3-O)(μ3-CO)(CO)18]

AU - Goudsmit, Robert J.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Whitmire, Kenton H.

PY - 1983

Y1 - 1983

N2 - The cluster [Os6(CO)20] reacts with molecular oxygen to give [Os6(μ3-O)(μ3-CO)(CO) 18], which has been shown by an X-ray analysis to contain an Os 6 raft, the central triangle of which is capped on one side by an O atom and on the other by a carbonyl group; this oxygenated cluster reacts with P(OMe) 3 to yield the clusters [Os6(CO) 21-n{P(OMe)3}n] (n = 1-6) and the cluster [Os6(CO)20] also reacts with acetylene to give [Os 4(CO)12(C2H2)] and [Os 5(CO)13(C2H2)2] and with hydrogen sulphide to give [H2Os3(CO)9S].

AB - The cluster [Os6(CO)20] reacts with molecular oxygen to give [Os6(μ3-O)(μ3-CO)(CO) 18], which has been shown by an X-ray analysis to contain an Os 6 raft, the central triangle of which is capped on one side by an O atom and on the other by a carbonyl group; this oxygenated cluster reacts with P(OMe) 3 to yield the clusters [Os6(CO) 21-n{P(OMe)3}n] (n = 1-6) and the cluster [Os6(CO)20] also reacts with acetylene to give [Os 4(CO)12(C2H2)] and [Os 5(CO)13(C2H2)2] and with hydrogen sulphide to give [H2Os3(CO)9S].

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Synthesis, reactivity, and molecular structure of the raft complex [Os ₆(μ₃-O)(μ₃-CO)(CO)₁₈]

Abstract

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