Abstract
Title full: Synthesis of the dimetal compounds [FeW{μ-PPh2 · CH · CH2 C(C6H4Me-4)}(CO)5(η5- C5Me5)] and [FeMo{μ-PPh2 · CH · CH2 · C(C6H4Me-4)}(CO)5(η5- C5H5)]; molecular structure of the iron-tungsten compound. Reactions between diphenyl(vinyl)phosphine and the compounds [FeW(μ-CC6H4Me-4)(CO)5(η 5-C5Me5)] and [FeMo(μ-CC6H4Me-4)(CO)6(η 5-C5H5)] result in a coupling of the vinyl and p-tolylmethylidyne groups at the dimetal centres to produce the PPh2 · CH · CH2 · C(C6H4Me-4) fragment, which bridges the metal-metal bonds. This was confirmed by an X-ray diffraction study on [FeW{μ-PPh2 · CH · CH2 · C(C6H4Me-4)}(CO)5(η5- C5Me5)].
Original language | English |
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Pages (from-to) | 2067-2071 |
Number of pages | 5 |
Journal | Polyhedron |
Volume | 6 |
Issue number | 12 |
DOIs | |
Publication status | Published - 1987 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry