Synthesis of the C1-C16 fragment of the ajudazols

B A Egan, M Paradowski, Lynne H Thomas, R Marquez

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Abstract

The synthesis of the C1-C16 framework of the ajudazols has been achieved taking advantage of a highly selective isobenzofuran oxidative rearrangement and a key Stille coupling to introduce the key C14-C15 bond.
Original languageEnglish
Pages (from-to)9700-9707
Number of pages8
JournalTetrahedron
Volume67
Issue number50
DOIs
Publication statusPublished - 16 Dec 2011

Keywords

  • oxidative rearrangement
  • isobenzofuran
  • ajudazol

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