Synthesis of the μ-PH hexaosmium clusters [Os6H 2(CO)20L(μ3-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os6H 2(CO)20(MeCN)(μ3-PH)] and [Os 6H3(CO)19(CO2Me)(μ3- PH)]

Christine J. Cardin; Stephen B. Colbran; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/C39860001288

Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]

Christine J. Cardin
, Stephen B. Colbran
, Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Mild heating of the phosphidotriosmium cluster [Os₃H(CO) ₁₀(μ₂-PH₂)] (1) with [Os₃(CO) _12-n(MeCN)_n] (n = 1 or 2) gives high yields of the (μ₃-PH) bridged hexaosmium clusters (2) and (3); reactions of (2) and (3) with bases and X-ray structure analyses of (3) and of (6), which was obtained from (3) and MeO^- followed by acid treatment are described.

Original language	English
Pages (from-to)	1288-1290
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39860001288
Publication status	Published - 31 Dec 1986

ASJC Scopus subject areas

Molecular Medicine

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Cardin, C. J., Colbran, S. B., Johnson, B. F. G., Lewis, J., & Raithby, P. R. (1986). Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]. Journal of the Chemical Society, Chemical Communications, (16), 1288-1290. https://doi.org/10.1039/C39860001288

Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]. / Cardin, Christine J.; Colbran, Stephen B.; Johnson, Brian F.G. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 31.12.1986, p. 1288-1290.

Research output: Contribution to journal › Article › peer-review

Cardin, CJ, Colbran, SB, Johnson, BFG, Lewis, J & Raithby, PR 1986, 'Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]', Journal of the Chemical Society, Chemical Communications, no. 16, pp. 1288-1290. https://doi.org/10.1039/C39860001288

Cardin CJ, Colbran SB, Johnson BFG, Lewis J, Raithby PR. Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base: X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]. Journal of the Chemical Society, Chemical Communications. 1986 Dec 31;(16):1288-1290. doi: 10.1039/C39860001288

Cardin, Christine J. ; Colbran, Stephen B. ; Johnson, Brian F.G. et al. / Synthesis of the μ-PH hexaosmium clusters [Os₆H ₂(CO)₂₀L(μ₃-PH)] (L = CO or MeCN) and their reactions with base : X-ray crystal structures of [Os₆H ₂(CO)₂₀(MeCN)(μ₃-PH)] and [Os ₆H₃(CO)₁₉(CO₂Me)(μ₃- PH)]. In: Journal of the Chemical Society, Chemical Communications. 1986 ; No. 16. pp. 1288-1290.

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