Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

Teresa M. Layer; Jack Lewis; Avelino Martín; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(93)83100-A

Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os₅(μ-H) (CO)₁₅(μ₃-SePh)] and [Os₆(μ-H)(CO)₁₈(μ-SeH)]

Teresa M. Layer
, Jack Lewis
, Avelino Martín
, Paul R. Raithby
, Wing Tak Wong

University of Cambridge
Chinese University of Hong Kong

Research output: Contribution to journal › Article › peer-review

Abstract

The neutral osmium-selenido clusters [Os₅(μ-H)(CO)₁₅(μ₃-SePh)] (2) and [Os₆(μ₃-H)(CO)₁₈(μ₃-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os₅H(CO)₁₅]^- and [Os₆H(CO)₁₅]^·- respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

Original language	English
Pages (from-to)	C57-C59
Journal	Journal of Organometallic Chemistry
Volume	444
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)83100-A
Publication status	Published - 9 Feb 1993

Funding

We gratefullya cknowledgefi nancials upportf or this work (to TML) from the Science and Engineering Council and I.C.I. plc. W-T.W acknowledgetsh e financial supporto f The Hong Kong ResearchG rant Council and the Universityo f Hong Kong.

Funders
Haringey Council

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(93)83100-A

Cite this

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title = "Synthesis of novel selenium-containing osmium carbonyl clusters: X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]",

abstract = "The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]- and [Os6H(CO)15]·- respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.",

author = "Layer, \{Teresa M.\} and Jack Lewis and Avelino Mart{\'i}n and Raithby, \{Paul R.\} and Wong, \{Wing Tak\}",

year = "1993",

month = feb,

day = "9",

doi = "10.1016/0022-328X(93)83100-A",

language = "English",

volume = "444",

pages = "C57--C59",

journal = "Journal of Organometallic Chemistry",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis of novel selenium-containing osmium carbonyl clusters

T2 - X-ray structures of [Os5(μ-H) (CO)15(μ3-SePh)] and [Os6(μ-H)(CO)18(μ-SeH)]

AU - Layer, Teresa M.

AU - Lewis, Jack

AU - Martín, Avelino

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1993/2/9

Y1 - 1993/2/9

N2 - The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]- and [Os6H(CO)15]·- respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

AB - The neutral osmium-selenido clusters [Os5(μ-H)(CO)15(μ3-SePh)] (2) and [Os6(μ3-H)(CO)18(μ3-SeH)] (5) have been isolated in good yield by reaction of PhSeCl with [Os5H(CO)15]- and [Os6H(CO)15]·- respectively. The structures of 2 and 5 have been established by single crystal X-ray analysis.

UR - https://www.scopus.com/pages/publications/0001964266

U2 - 10.1016/0022-328X(93)83100-A

DO - 10.1016/0022-328X(93)83100-A

M3 - Article

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VL - 444

SP - C57-C59

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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