Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C5H5)Fe(C5H4)C≡CMn(CO) 3{Ph2PCH(Me)CH2PPh2}] which has potential for second-order non-linear optics

Michael C.B. Colbert; Andrew J. Edwards; Jack Lewis; Nicholas J. Long; Nicola A. Page; David G. Parker; Paul R. Raithby

doi:10.1039/DT9940002589

Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] which has potential for second-order non-linear optics

Michael C.B. Colbert, Andrew J. Edwards, Jack Lewis, Nicholas J. Long, Nicola A. Page, David G. Parker, Paul R. Raithby

Research output: Contribution to journal › Article › peer-review

Abstract

Three novel manganese(I) ferrocenylacetylide complexes have been synthesised and characterised and the crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] has been determined, in which the incorporation of a chiral chelating phosphine leads to crystallisation in the non-centrosymmetric space group P2₁2₁2₁.

Original language	English
Pages (from-to)	2589-2590
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	17
DOIs	https://doi.org/10.1039/DT9940002589
Publication status	Published - 1994

ASJC Scopus subject areas

General Chemistry

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Colbert, M. C. B., Edwards, A. J., Lewis, J., Long, N. J., Page, N. A., Parker, D. G., & Raithby, P. R. (1994). Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] which has potential for second-order non-linear optics. Journal of the Chemical Society, Dalton Transactions, (17), 2589-2590. https://doi.org/10.1039/DT9940002589

Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] which has potential for second-order non-linear optics. / Colbert, Michael C.B.; Edwards, Andrew J.; Lewis, Jack et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 17, 1994, p. 2589-2590.

Research output: Contribution to journal › Article › peer-review

Colbert, MCB, Edwards, AJ, Lewis, J, Long, NJ, Page, NA, Parker, DG & Raithby, PR 1994, 'Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] which has potential for second-order non-linear optics', Journal of the Chemical Society, Dalton Transactions, no. 17, pp. 2589-2590. https://doi.org/10.1039/DT9940002589

Colbert MCB, Edwards AJ, Lewis J, Long NJ, Page NA, Parker DG et al. Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C₅H₅)Fe(C₅H₄)C≡CMn(CO) ₃{Ph₂PCH(Me)CH₂PPh₂}] which has potential for second-order non-linear optics. Journal of the Chemical Society, Dalton Transactions. 1994;(17):2589-2590. doi: 10.1039/DT9940002589

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title = "Synthesis of novel donor-acceptor manganese(I) complexes of ferrocenylacetylene: Crystal structure of [(C5H5)Fe(C5H4)C≡CMn(CO) 3\{Ph2PCH(Me)CH2PPh2\}] which has potential for second-order non-linear optics",

abstract = "Three novel manganese(I) ferrocenylacetylide complexes have been synthesised and characterised and the crystal structure of [(C5H5)Fe(C5H4)C≡CMn(CO) 3\{Ph2PCH(Me)CH2PPh2\}] has been determined, in which the incorporation of a chiral chelating phosphine leads to crystallisation in the non-centrosymmetric space group P212121.",

author = "Colbert, \{Michael C.B.\} and Edwards, \{Andrew J.\} and Jack Lewis and Long, \{Nicholas J.\} and Page, \{Nicola A.\} and Parker, \{David G.\} and Raithby, \{Paul R.\}",

year = "1994",

doi = "10.1039/DT9940002589",

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AU - Edwards, Andrew J.

AU - Lewis, Jack

AU - Long, Nicholas J.

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AU - Parker, David G.

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AB - Three novel manganese(I) ferrocenylacetylide complexes have been synthesised and characterised and the crystal structure of [(C5H5)Fe(C5H4)C≡CMn(CO) 3{Ph2PCH(Me)CH2PPh2}] has been determined, in which the incorporation of a chiral chelating phosphine leads to crystallisation in the non-centrosymmetric space group P212121.

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