Synthesis of cross linked platinum metal containing polyyne polymers

M. S. Khan; D. J. Schwartz; N. A. Pasha; A. K. Kakkar; B. Lin; P. R. Raithby; J. Lewis

doi:10.1002/zaac.19926161018

Synthesis of cross linked platinum metal containing polyyne polymers

M. S. Khan, D. J. Schwartz, N. A. Pasha, A. K. Kakkar, B. Lin, P. R. Raithby, J. Lewis

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of Pt(PⁿBu₃)₂Cl₂ (1) or Pt(AsⁿBu₃₂Cl₂ (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)₃C₆H₃] (3)yields monomeric, [1,3,5‐Cl(PⁿBu₃)₂(PtC C)₃C₆H₃] (4), [1,3,5‐(C1)(AsⁿBu₃)₂PtC C₃C₆H₃] (5) or polymeric, {1,3,5‐[(PⁿBu₃)₂PtCC]₃C₆H₃)ⁿ (6), {1,3,5‐[(AsⁿBu₃)₂PtC C]₃C₆H₃}ⁿ (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC₆H₂(CH₃)₂C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

Original language	English
Pages (from-to)	121-124
Number of pages	4
Journal	ZAAC ‐ Journal of Inorganic and General Chemistry
Volume	616
Issue number	10
DOIs	https://doi.org/10.1002/zaac.19926161018
Publication status	Published - 1992

Keywords

cross‐linked
electronic properties
polyyne copolymer
rigid‐rod
π‐conjugation
σ‐acetylide

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.19926161018

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@article{b12077be19084d32bfc5dceaeb4d9e0e,

title = "Synthesis of cross linked platinum metal containing polyyne polymers",

abstract = "Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.",

keywords = "cross‐linked, electronic properties, polyyne copolymer, rigid‐rod, π‐conjugation, σ‐acetylide",

author = "Khan, {M. S.} and Schwartz, {D. J.} and Pasha, {N. A.} and Kakkar, {A. K.} and B. Lin and Raithby, {P. R.} and J. Lewis",

year = "1992",

doi = "10.1002/zaac.19926161018",

language = "English",

volume = "616",

pages = "121--124",

journal = "ZAAC ‐ Journal of Inorganic and General Chemistry",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - Synthesis of cross linked platinum metal containing polyyne polymers

AU - Khan, M. S.

AU - Schwartz, D. J.

AU - Pasha, N. A.

AU - Kakkar, A. K.

AU - Lin, B.

AU - Raithby, P. R.

AU - Lewis, J.

PY - 1992

Y1 - 1992

N2 - Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

AB - Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

KW - cross‐linked

KW - electronic properties

KW - polyyne copolymer

KW - rigid‐rod

KW - π‐conjugation

KW - σ‐acetylide

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U2 - 10.1002/zaac.19926161018

DO - 10.1002/zaac.19926161018

M3 - Article

AN - SCOPUS:84984051908

SN - 0044-2313

VL - 616

SP - 121

EP - 124

JO - ZAAC ‐ Journal of Inorganic and General Chemistry

JF - ZAAC ‐ Journal of Inorganic and General Chemistry

IS - 10

ER -

Synthesis of cross linked platinum metal containing polyyne polymers

Abstract

Keywords

ASJC Scopus subject areas

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