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Transition-metal-catalyzed hydrogen-transfer reactions have been used for the conversion of alcohols into benzimidazoles and aldehydes into benzoxazoles and benzothiazoles.
Blacker, A. J., Farah, M. M., Hall, M. I., Marsden, S. P., Saidi, O., & Williams, J. M. J. (2009). Synthesis of Benzazoles by Hydrogen-Transfer Catalysis. Organic Letters, 11(9), 2039-2042. https://doi.org/10.1021/ol900557u