Synthesis of a triosmium carbonyl cluster complex with a side-on-coordinated imine ligand

Jochem U. Köhler; Jack Lewis; Paul R. Raithby; Moira A. Rennie

doi:10.1021/om961014+

Synthesis of a triosmium carbonyl cluster complex with a side-on-coordinated imine ligand

Jochem U. Köhler, Jack Lewis, Paul R. Raithby, Moira A. Rennie

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11 Citations (SciVal)

Abstract

A triosmium cluster with a novel side-on coordinated imine ligand has been synthesized by the reaction between a triosmium carbene complex and ammonia. In the first step of the reaction, an anionic amino complex is formed which reacts upon treatment with [Ph₃C]⁺ to abstract a hydride from the amino group to form the imine complex, the molecular structure of which has been determined.

Original language	English
Pages (from-to)	3851-3854
Number of pages	4
Journal	Organometallics
Volume	16
Issue number	17
DOIs	https://doi.org/10.1021/om961014+
Publication status	Published - 1 Aug 1997

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om961014+

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title = "Synthesis of a triosmium carbonyl cluster complex with a side-on-coordinated imine ligand",

abstract = "A triosmium cluster with a novel side-on coordinated imine ligand has been synthesized by the reaction between a triosmium carbene complex and ammonia. In the first step of the reaction, an anionic amino complex is formed which reacts upon treatment with [Ph3C]+ to abstract a hydride from the amino group to form the imine complex, the molecular structure of which has been determined.",

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AU - Köhler, Jochem U.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Rennie, Moira A.

PY - 1997/8/1

Y1 - 1997/8/1

N2 - A triosmium cluster with a novel side-on coordinated imine ligand has been synthesized by the reaction between a triosmium carbene complex and ammonia. In the first step of the reaction, an anionic amino complex is formed which reacts upon treatment with [Ph3C]+ to abstract a hydride from the amino group to form the imine complex, the molecular structure of which has been determined.

AB - A triosmium cluster with a novel side-on coordinated imine ligand has been synthesized by the reaction between a triosmium carbene complex and ammonia. In the first step of the reaction, an anionic amino complex is formed which reacts upon treatment with [Ph3C]+ to abstract a hydride from the amino group to form the imine complex, the molecular structure of which has been determined.

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U2 - 10.1021/om961014+

DO - 10.1021/om961014+

M3 - Article

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JO - Organometallics

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ER -

Synthesis of a triosmium carbonyl cluster complex with a side-on-coordinated imine ligand

Abstract

ASJC Scopus subject areas

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