Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

K S Coleman; S Turberville; Sofia I Pascu; M L H Green

doi:10.1016/j.jorganchem.2004.10.019

Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

K S Coleman, S Turberville, Sofia I Pascu, M L H Green

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (SciVal)

Abstract

A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

Original language	English
Pages (from-to)	653-658
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	3
DOIs	https://doi.org/10.1016/j.jorganchem.2004.10.019
Publication status	Published - 2005

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Coleman, K. S., Turberville, S., Pascu, S. I., & Green, M. L. H. (2005). Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene. Journal of Organometallic Chemistry, 690(3), 653-658. https://doi.org/10.1016/j.jorganchem.2004.10.019

Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene. / Coleman, K S; Turberville, S; Pascu, Sofia I et al.
In: Journal of Organometallic Chemistry, Vol. 690, No. 3, 2005, p. 653-658.

Research output: Contribution to journal › Article › peer-review

Coleman, KS, Turberville, S, Pascu, SI & Green, MLH 2005, 'Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene', Journal of Organometallic Chemistry, vol. 690, no. 3, pp. 653-658. https://doi.org/10.1016/j.jorganchem.2004.10.019

Coleman KS, Turberville S, Pascu SI, Green MLH. Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene. Journal of Organometallic Chemistry. 2005;690(3):653-658. doi: 10.1016/j.jorganchem.2004.10.019

Coleman, K S ; Turberville, S ; Pascu, Sofia I et al. / Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene. In: Journal of Organometallic Chemistry. 2005 ; Vol. 690, No. 3. pp. 653-658.

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title = "Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene",

abstract = "A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.",

author = "Coleman, {K S} and S Turberville and Pascu, {Sofia I} and Green, {M L H}",

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T1 - Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

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AU - Pascu, Sofia I

AU - Green, M L H

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N2 - A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

AB - A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

UR - http://dx.doi.org/10.1016/j.jorganchem.2004.10.019

U2 - 10.1016/j.jorganchem.2004.10.019

DO - 10.1016/j.jorganchem.2004.10.019

M3 - Article

SN - 0022-328X

VL - 690

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EP - 658

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

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