Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

K S Coleman, S Turberville, Sofia I Pascu, M L H Green

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Abstract

A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.
Original languageEnglish
Pages (from-to)653-658
Number of pages6
JournalJournal of Organometallic Chemistry
Volume690
Issue number3
DOIs
Publication statusPublished - 2005

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Gadiformes
dichlorides
Palladium
carbenes
caps
palladium
Ligands
Salts
salts
ligands
synthesis
palladium chloride
carbene
ferrocene
1,5-cyclooctadiene

Cite this

@article{210d858dff134760802e54f92f4c85b1,
title = "Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene",
abstract = "A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.",
author = "Coleman, {K S} and S Turberville and Pascu, {Sofia I} and Green, {M L H}",
year = "2005",
doi = "10.1016/j.jorganchem.2004.10.019",
language = "English",
volume = "690",
pages = "653--658",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "3",

}

TY - JOUR

T1 - Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene

AU - Coleman, K S

AU - Turberville, S

AU - Pascu, Sofia I

AU - Green, M L H

PY - 2005

Y1 - 2005

N2 - A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

AB - A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

UR - http://dx.doi.org/10.1016/j.jorganchem.2004.10.019

U2 - 10.1016/j.jorganchem.2004.10.019

DO - 10.1016/j.jorganchem.2004.10.019

M3 - Article

VL - 690

SP - 653

EP - 658

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 3

ER -