Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Reaction of two molar equivalents of [KN(SiMe3)2] and a mixture of [CH2(Ph2P═NC6H2-Me3-2,4,6)2] and SmI2 in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.

Original languageEnglish
Pages (from-to)4570-4571
Number of pages2
JournalJournal of the Chemical Society. Dalton Transactions
Volume3
Issue number24
DOIs
Publication statusPublished - 2 Dec 2003

Keywords

  • Lanthanides
  • Organometallic
  • P, N, S, Se, O, Te, Si-containing ligands
  • Samarium
  • X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)

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