Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

Michael S. Hill; Peter B. Hitchcock

doi:10.1039/b313034g

Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

Reaction of two molar equivalents of [KN(SiMe₃)₂] and a mixture of [CH₂(Ph₂P═NC₆H₂-Me₃-2,4,6)₂] and SmI₂ in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.

Original language	English
Pages (from-to)	4570-4571
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	3
Issue number	24
DOIs	https://doi.org/10.1039/b313034g
Publication status	Published - 2 Dec 2003

Keywords

Lanthanides
Organometallic
P, N, S, Se, O, Te, Si-containing ligands
Samarium
X-ray diffraction

ASJC Scopus subject areas

General Chemistry

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10.1039/b313034g

Cite this

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title = "Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide",

abstract = "Reaction of two molar equivalents of [KN(SiMe3)2] and a mixture of [CH2(Ph2P═NC6H2-Me3-2,4,6)2] and SmI2 in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.",

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AU - Hitchcock, Peter B.

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N2 - Reaction of two molar equivalents of [KN(SiMe3)2] and a mixture of [CH2(Ph2P═NC6H2-Me3-2,4,6)2] and SmI2 in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.

AB - Reaction of two molar equivalents of [KN(SiMe3)2] and a mixture of [CH2(Ph2P═NC6H2-Me3-2,4,6)2] and SmI2 in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.

KW - Lanthanides

KW - Organometallic

KW - P, N, S, Se, O, Te, Si-containing ligands

KW - Samarium

KW - X-ray diffraction

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M3 - Article

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ER -

Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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