Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents

Georgina L. Gregory; Marion Ulmann; Antoine Buchard

doi:10.1039/C5RA07290E

Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents

Georgina L. Gregory, Marion Ulmann, Antoine Buchard

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66 Citations (SciVal)

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Abstract

Low pressure carbon dioxide is used as the carbonation agent in a
simple, safe and efficient procedure for the synthesis of 6-membered
cyclic carbonates from 1,3-diols. Using readily available reagents and
proceeding at room temperature, this route offers a novel mild
alternative to phosgene derivatives.

Original language	English
Pages (from-to)	39404-39408
Number of pages	5
Journal	RSC Advances
Volume	5
Issue number	49
Early online date	24 Apr 2015
DOIs	https://doi.org/10.1039/C5RA07290E
Publication status	Published - 24 Apr 2015

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10.1039/C5RA07290E

Supporting Information_Gregory et alSubmitted manuscript, 2.36 MB
c5ra07290eFinal published version, 477 KBLicence: CC BY

Cite this

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title = "Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents",

abstract = "Low pressure carbon dioxide is used as the carbonation agent in asimple, safe and efficient procedure for the synthesis of 6-memberedcyclic carbonates from 1,3-diols. Using readily available reagents andproceeding at room temperature, this route offers a novel mildalternative to phosgene derivatives.",

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N2 - Low pressure carbon dioxide is used as the carbonation agent in asimple, safe and efficient procedure for the synthesis of 6-memberedcyclic carbonates from 1,3-diols. Using readily available reagents andproceeding at room temperature, this route offers a novel mildalternative to phosgene derivatives.

AB - Low pressure carbon dioxide is used as the carbonation agent in asimple, safe and efficient procedure for the synthesis of 6-memberedcyclic carbonates from 1,3-diols. Using readily available reagents andproceeding at room temperature, this route offers a novel mildalternative to phosgene derivatives.

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Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents

Abstract

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DFT study of the reaction between DBU, CO2 and (R)-1,3-butanediol to form cyclic carbonate (R)-4-Methyl-[1,3]-dioxan-2-one

DFT study of the tosylation and cyclisation steps in the synthesis of cyclic carbonate (R)-4-Methyl-[1,3]-dioxan-2-one from CO2 and (R)-1,3-butanediol

High Performance Computing (HPC) Facility

MC2-Mass Spectrometry (MS)

MC2- Nuclear Magnetic Resonance (NMR)

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Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents

Abstract

Access to Document

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Datasets

DFT study of the reaction between DBU, CO2 and (R)-1,3-butanediol to form cyclic carbonate (R)-4-Methyl-[1,3]-dioxan-2-one

DFT study of the tosylation and cyclisation steps in the synthesis of cyclic carbonate (R)-4-Methyl-[1,3]-dioxan-2-one from CO2 and (R)-1,3-butanediol

Equipment

High Performance Computing (HPC) Facility

MC2-Mass Spectrometry (MS)

MC2- Nuclear Magnetic Resonance (NMR)

Cite this